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Perkin Transactions 2 1972-2002 logo

Year 1975
Main Index

Issue 0


Index of authors, 1975

pg 1877; DOI:
10.1039/P29750001877
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Index of subjects, 1975

pg 1893; DOI:
10.1039/P29750001893
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Issue 1


Front cover

pg X001; DOI:
10.1039/P297500FX001
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Contents pages

pg P001; DOI:
10.1039/P297500FP001
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The thermal decomposition of cis- and trans-2-methoxy-4-methyl-3,4-dihydro-2H-pyran
John F. Collins Henry M. Frey and Neil S. Isaacs
pg 1; DOI:
10.1039/P29750000001
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Back cover

pg X003; DOI:
10.1039/P297500BX003
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Synthesis and thermolysis of rhodium and iridium complexes of endo-6-vinylbicyclo[3.1.0]hex-2-ene. A metal-promoted vinylcyclopropane to cyclopentene rearrangement
Vanessa Aris John M. Brown John A. Conneely Bernard T. Golding and David H. Williamson
pg 4; DOI:
10.1039/P29750000004
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Directive effects in benzylic hydrogen atom abstraction. Part VI. Halogenation of arethyl fluorides
Kheng H. Lee S. E. Loke and G. H. Yeoh
pg 10; DOI:
10.1039/P29750000010
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Infrared carbonyl absorptions of 2-oxofurans: fermi resonance versus rotational isomerism as the cause of carbonyl band doubling in furan-2-carbaldehyde and related aldehydes
Derek J. Chadwick John Chambers G. Denis Meakins and Roger L. Snowden
pg 13; DOI:
10.1039/P29750000013
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Crystal structures of some acid salts of monobasic acids. Part XVII. Structure of sodium hydrogen diacetate, redetermined by neutron diffraction
Michael J. Barrow Murdoch Currie Kenneth W. Muir J. Clare Speakman and David N. J. White
pg 15; DOI:
10.1039/P29750000015
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Autoxidation of 5-methyl-5,6,7,8-tetrahydrofolic acid
John A. Blair Anthony J. Pearson and Anthony J. Robb
pg 18; DOI:
10.1039/P29750000018
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Carbon-13 nuclear magnetic resonance spectroscopy of polymers. Part IV. Peak assignment for styrene–butadiene copolymers
Alan Roy Katritzky and Douglas Eugene Weiss
pg 21; DOI:
10.1039/P29750000021
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Carbon-13 nuclear magnetic resonance spectroscopy of polymers. Part V. Monomer sequence in styrene–butadiene copolymers
Alan Roy Katritzky and Douglas Eugene Weiss
pg 27; DOI:
10.1039/P29750000027
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The photochemistry of phosphorus compounds. Part X. Photolysis of disodium -D-glucose 6-phosphate in aqueous solution under nitrogen or oxygen
Christian Triantaphylides and Mordehai Halmann
pg 34; DOI:
10.1039/P29750000034
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Redetermination of the crystal and molecular structure of pteridine
Charles D. Shirrell and Donald E. Williams
pg 40; DOI:
10.1039/P29750000040
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The molecular conformation of cyclodi--alanyl
David N. J. White and Michael H. P. Guy
pg 43; DOI:
10.1039/P29750000043
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The thermal decomposition of azodicarbonamide (1,1-azobisformamide)
A. Sant Prakash William A. Swam and Alec N. Strachan
pg 46; DOI:
10.1039/P29750000046
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Conformational analysis by carbon-13 nuclear magnetic resonance spectroscopy. Part I. Hexahydro-3H-oxazolo[3,4-a] pyridines
Yoshito Takeuchi Peter J. Chivers and Trevor A. Crabb
pg 51; DOI:
10.1039/P29750000051
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The acidities of weak acids. Part I. A new method for determining pKa values in the range 12–24
Derek W. Earls John R. Jones Trevor G. Rumney and Anthony F. Cockerill
pg 54; DOI:
10.1039/P29750000054
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Molecular conformation of S-4-nitrophenyl OO-diphenyl thiophosphate: X-ray crystal structure analysis
Ramsey Gitany and Rognvald S. McEwen
pg 57; DOI:
10.1039/P29750000057
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Crystal structure of N-(5-O-phosphopyridoxyl)-L-tyrosine heptahydrate
Alessandro Mangia Mario Nardelli Giancarlo Pelizzi Carla Borri Voltattorni Aldo Orlacchio and Carlo Turano
pg 60; DOI:
10.1039/P29750000060
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1H and 13C nuclear magnetic resonance shift measurements and association constants of some chloroform, trinitromethane, pentachloroethane, and 1,1,1-trichloro-2,2-bis-(p-chlorophenyl)ethane (DDT) complexes in cyclohexane solution
Alan A. S. Bright Roy Foster and John A. Chudek
pg 64; DOI:
10.1039/P29750000064
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Structure refinement and molecular packing of p-chloro-trans-cinnamic acid and -(p-chlorophenyl)propionic acid
Jenny Pickworth Glusker David E. Zacharias and Horace L. Carrell
pg 68; DOI:
10.1039/P29750000068
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Adamantane chemistry. Part II. X-Ray structure analysis of 5-chloromethyl-4-oxahomoadamantan-5-ol
Michael J. Begley G. Bryon Gill and David C. Woods
pg 74; DOI:
10.1039/P29750000074
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Electron spin resonance study of the fragmentation of some cyclic and acyclic dialkoxyalkyl radicals. The mechanism of 1,2-rearrangement of -acyloxyalkyl radicals
M. John Perkins and Brian P. Roberts
pg 77; DOI:
10.1039/P29750000077
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Role of imperfections in the dimerization of substituted anthracenes. Part II. 1,8-Dichloro-10-methylanthracene
John M. Thomas John O. Williams Jean-Pierre Desvergne Guilio Guarini and Henri Bouas-Laurent
pg 84; DOI:
10.1039/P29750000084
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Crystal and molecular structure of tricarbonyl(8,8-dibromobicyclo-[5.1.0]octa-2,4-diene)iron
Paul Skarstad P. Janse-van Vuuren Jerrold Meinwald and Robert E. Hughes
pg 88; DOI:
10.1039/P29750000088
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Issue 2


Front cover

pg X005; DOI:
10.1039/P297500FX005
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Contents pages

pg P005; DOI:
10.1039/P297500FP005
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Back cover

pg X007; DOI:
10.1039/P297500BX007
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Crystal structure and absolute configuration of lycopodine hydrochloride
Mazhar Ul Haque and Donald Rogers
pg 93; DOI:
10.1039/P29750000093
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Unimolecular gas-phase hydrogen randomization within 2-methyl-propane radical cations
Peter J. Derrick A. M. Falick and A. L. Burlingame
pg 98; DOI:
10.1039/P29750000098
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Electron spin resonance study of radicals obtained from the oxidation of naturally occurring hydroxypyrones
William T. Dixon Majid Moghimi and D. Murphy
pg 101; DOI:
10.1039/P29750000101
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The oxidative cyclization of formazans to tetrazolium salts
Anthony F. Hegarty John H. Coy and Francis L. Scott
pg 104; DOI:
10.1039/P29750000104
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Kinetics and mechanism of the Fischer–Hepp rearrangement and denitrosation. Part V. The mechanism of denitrosation
Ian D. Biggs and D. Lyn H. Williams
pg 107; DOI:
10.1039/P29750000107
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Conformational equilibria in N-alkyl-cis-decahydroquinolines
Harold Booth and D. Vaughan Griffiths
pg 111; DOI:
10.1039/P29750000111
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Conformational studies of quaternary ammonium ions. Part II. Molecular mechanical calculation of conformation energies of -substituted ethyltrimethylammonium ions
Yoshihiro Terui
pg 118; DOI:
10.1039/P29750000118
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Conformational studies of quaternary ammonium ions. Part III. Conformational analyses of substituted piperidinium ions by 1H nuclear magnetic resonance spectroscopy and evaluation of the contribution of electrostatic interaction energy in controlling conformation
Yoshihiro Terui and Kazuo Tori
pg 127; DOI:
10.1039/P29750000127
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Equilibrium addition of nucleophiles to carbon–nitrogen double bonds. Kinetics of the addition of propanethiol to benzylideneanilines in non-aqueous solutions
Yoshiro Ogata and Atsushi Kawasaki
pg 134; DOI:
10.1039/P29750000134
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An electron spin resonance study of the structure and reactivity of aminophosphoranyl radicals in solution
Robert W. Dennis and Brian P. Roberts
pg 140; DOI:
10.1039/P29750000140
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The chemistry of nitroso-compounds. Part IX. General acid catalysed decomposition of N-nitroso-2-pyrrolidone, an example of amide hydrolysis via SN2 displacement on the N-conjugate acid
Brian C. Challis and Susan P. Jones
pg 153; DOI:
10.1039/P29750000153
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Electro-organic reactions. Part III. Mechanistic aspects of the cathodic hydrogenation of activated carbon–carbon double bonds
L. Alberto Avaca and James H. P. Utley
pg 161; DOI:
10.1039/P29750000161
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Amphielectronic ionization of a -radical, a basis for correlating radical with nucleophilic and/or electrophilic reactivities
Constantinos G. Screttas
pg 165; DOI:
10.1039/P29750000165
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Issue 3


Front cover

pg X009; DOI:
10.1039/P297500FX009
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Contents pages

pg P009; DOI:
10.1039/P297500FP009
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Back cover

pg X011; DOI:
10.1039/P297500BX011
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Kinetics of desulphuration of ethylthiourea in sodium hydroxide studied by a radiochromatographic method
Raffaele Battistuzzi Giuseppe Marcotrigiano and Giorgio Peyronel
pg 169; DOI:
10.1039/P29750000169
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Radiation chemistry of ethers. Part VI. Photolysis at 254 nm of the diethyl ether–oxygen charge transfer complex
Clemens von Sonntag Klaus Neuwald Heinz-Peter Schuchmann Fritz Weeke and Edo Janssen
pg 171; DOI:
10.1039/P29750000171
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Sulphone structures. Part II. Crystal and molecular structure of N-p-tolylsulphonylbenzylamine, 1-methyl-3-p-tolylsulphonylaminoindole, 1-methyl-3-p-tolylsulphonyliminoindoline-2-spirocyclopentane, and 1,2,3,4-tetrahydro-1,2,4-trimethyl-4-p-tolylsulphonylamino-3-p-tolylsulphonyliminoquinoline
T. Stanley Cameron Keith Prout Barry Denton Ricardo Spagna and Esther White
pg 176; DOI:
10.1039/P29750000176
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A nuclear magnetic resonance study of the addition of methanol and methoxide ions to substituted benzaldehydes, and corresponding JM acidity function values
Michael R. Crampton
pg 185; DOI:
10.1039/P29750000185
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Chemistry of the SO bond. Part IV. Conformational analysis of ethylene sulphites
Christopher H. Green and Desmond G. Hellier
pg 190; DOI:
10.1039/P29750000190
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Theoretical studies on ion pairs. An ab-initio investigation of the lithium–formaldehyde ion pair
Fernando Bernardi and Gian Franco Pedulli
pg 194; DOI:
10.1039/P29750000194
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The preparation of exo- and endo-6-bromo-3-oxabicyclo[3.1.0]hexanes and their stereospecific reactions with butyl-lithium
H. Maskill
pg 197; DOI:
10.1039/P29750000197
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The nuclear magnetic resonance spectra of porphyrins. Part X. Carbon-13 nuclear magnetic resonance spectra of some meso-tetraarylporphyrins and their metal chelates
Raymond J. Abraham Geoffrey E. Hawkes Mervyn F. Hudson and Kevin M. Smith
pg 204; DOI:
10.1039/P29750000204
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A kinetic study of the nucleophilicity of substituted arenethiols in reaction with p-nitrophenyl acetate
Giuseppe Guanti Carlo Dell'Erba Francesca Pero and Giuseppe Leandri
pg 212; DOI:
10.1039/P29750000212
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Electrochemical reactions. Part XVIII. Reductive cleavage of aromatic carbon–halogen bonds in the presence of deuterium oxide
James Grimshaw and Jadwiga Trocha-Grimshaw
pg 215; DOI:
10.1039/P29750000215
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Kinetics of -chlorination of sulphoxides by N-chlorobenzotriazole
Dario Landini and Angela Maia
pg 218; DOI:
10.1039/P29750000218
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Dehydrohalogenation of threo- and erythro-1-chloro-and 1-bromo-1,2-diphenyl-2-p-tolylsulphonylethanes. A survey of the stereochemical course
Vito Fiandanese Carmine V. Maffeo Giuseppe Marchese and Francesco Naso
pg 221; DOI:
10.1039/P29750000221
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Solutes in sulphuric acid. Part VI. A nuclear magnetic resonance study of organic sulphonic acids and 1H nuclear magnetic resonance standards; pKBH determination of sulphonic acids
Ankie Koeberg-Telder and Hans Cerfontain
pg 226; DOI:
10.1039/P29750000226
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Mesoionic compounds. Part IV. Acid catalysed hydrolysis and protonation behaviour of 4,5-diarylisosydnones
Emmanuel A. Isukul and John G. Tillett
pg 230; DOI:
10.1039/P29750000230
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The substituent dependence of the primary deuterium kinetic isotope effect in elimination from phenethyl bromides and dimethyl(phenethyl)-sulphonium bromides in 502 mole % dimethyl sulphoxide–water
Leonard F. Blackwell and John L. Woodhead
pg 234; DOI:
10.1039/P29750000234
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Interactions of cations with sugar anions. Part I. Crystal structures of calcium sodium galacturonate hexahydrate and strontium sodium galacturonate hexahydrate
Sheila E. B. Gould Robert O. Gould David A. Rees and William E. Scott
pg 237; DOI:
10.1039/P29750000237
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Kinetics of the reactions of picryl chloride with substituted benzoate ions
Triyama Ranjan Mohanty and Padina Lochan Nayak
pg 242; DOI:
10.1039/P29750000242
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Non-enzymatic, tetrahydrobiopterin-mediated hydroxylation of phenylalanine
John A. Blair and Anthony J. Pearson
pg 245; DOI:
10.1039/P29750000245
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Hydrogen-bonded species of the complex of 4-methylpyridine with dichloroacetic acid in toluene at 35
Z. Dega-Szafran E. Grech M. Z. Naskret-Barciszewska and Mirosaw Szafran
pg 250; DOI:
10.1039/P29750000250
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Phenolysis and competing methanolysis of optically active 1-phenylethyl chloride in sterically hindered 2,6-dialkylphenol solvents
Kunio Okamoto Tomomi Kinoshita and Yasuo Osada
pg 253; DOI:
10.1039/P29750000253
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Electron nuclear double resonance and electron spin resonance studies of anion-radicals derived from p-benzoquinone
Neil M. Atherton and Pamela A. Henshaw
pg 258; DOI:
10.1039/P29750000258
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Issue 4


Front cover

pg X013; DOI:
10.1039/P297500FX013
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Contents pages

pg P013; DOI:
10.1039/P297500FP013
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Back cover

pg X015; DOI:
10.1039/P297500BX015
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Crystal structures of complexes between alkali-metal salts and cyclic polyethers. Part VIII. Complexes formed by caesium thiocyanate with (7R,9R,18S,20S)-6,7,9,10,17,18,20,21-octahydro-7,9,18,20-tetramethyldibenzo[b,k][1,4,7,10,13,16]hexaoxacyclo-octadecin (tetramethyldibenzo-18-crown-6, isomer F) and its (18R,20R)-isomer (isomer G)
Paul R. Mallinson
pg 261; DOI:
10.1039/P29750000261
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Crystal structure of (7R,9R,18S,20S)-6,7,9,10,17,18,20,21-octahydro-7,9,18,20-tetramethyldibenzo[b,k][1,4,7,10,13,16]hexaoxacyclo-octadecin (tetramethyldibenzo-18-crown-6, isomer F)
Paul R. Mallinson
pg 266; DOI:
10.1039/P29750000266
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X-Ray crystal structure of hexahydro-1,4-dimethyl-s-tetrazine
Gerald B. Ansell and James L. Erickson
pg 270; DOI:
10.1039/P29750000270
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Nucleophilic attacks on carbon–carbon double bonds. Part XXI. Substitution of (E)--chloro--nitrostyrene by anilines in acetonitrile
Zvi Rappoport and Shmaryahu Hoz
pg 272; DOI:
10.1039/P29750000272
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Electrophilic aromatic reactivities via pyrolysis of 1-arylethyl acetates. Part X. Pyridine N-oxide
Roger Taylor
pg 277; DOI:
10.1039/P29750000277
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Hydrolysis of phthalic and 3,6-dimethylphthalic anhydrides
Malcolm D. Hawkins
pg 282; DOI:
10.1039/P29750000282
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Hydrolysis of 2,2,2-trifluoroethyl hydrogen 3,6-dimethylphthalate
Malcolm D. Hawkins
pg 285; DOI:
10.1039/P29750000285
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Influence of solvent on the electronic absorption and fluorescence spectra of trans-1-(4-NN-dimethylaminophenyl)-2-nitroethylene
David J. Cowley
pg 287; DOI:
10.1039/P29750000287
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Structure and conformational properties of some radicals from thiazolyl derivatives
Gian Franco Pedulli Paolo Zanirato Angelo Alberti and Marcello Tiecco
pg 293; DOI:
10.1039/P29750000293
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Kinetics of reactions in heterocycles. Part XII. Substituted N-methylquinolinium and N-methylisoquinolinium salts with hydroxide ions
Gordon B. Barlin and John A. Benbow
pg 298; DOI:
10.1039/P29750000298
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Electron spin resonance studies. Part XLIII. Reaction of dimethyl sulphoxide with the hydroxyl radical
Bruce C. Gilbert Richard O. C. Norman and Roger C. Sealy
pg 303; DOI:
10.1039/P29750000303
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Electron spin resonance studies. Part XLIV. The formation of alkylsulphonyl radicals by the oxidation of aliphatic sulphoxides with the hydroxyl radical and by the reaction of alkyl radicals with sulphur dioxide
Bruce C. Gilbert Richard O. C. Norman and Roger C. Sealy
pg 308; DOI:
10.1039/P29750000308
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Syntheses of alkoxotellurium (VI) fluorides, (RO)xTeF6 –x: importance of intramolecular electronic effects on the value of x
George W. Fraser and Gordon D. Meikle
pg 312; DOI:
10.1039/P29750000312
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Catalysis by hydrogen halides in the gas phase. Part XXVII. N-t-Butylacetamide and hydrogen chloride
Allan Maccoll and Surgit S. Nagra
pg 314; DOI:
10.1039/P29750000314
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The gas-phase pyrolysis of some primary and secondary thionacetates
David B. Bigley and Rosemary E Gabbott
pg 317; DOI:
10.1039/P29750000317
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Free radical addition to olefins. Part XV. Addition of bromoform and carbon tetrabromide to fluoroethylenes
David S. Ashton David J. Shand John M. Tedder and John C. Walton
pg 320; DOI:
10.1039/P29750000320
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Diazepines. Part XIX. Kinetics of addition of bromine to position 6 in 2,3-dihydro-1,4-diazepinium salts
Clive Barnett Donald R. Marshall and Douglas Lloyd
pg 325; DOI:
10.1039/P29750000325
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Elimination reactions of 1,2-diaryl-1-chloroethanes promoted by sodium ethoxide in ethanol. The kinetic effects of - and -phenyl substituents
Enrico Baciocchi Piero Perucci and Cesare Rol
pg 329; DOI:
10.1039/P29750000329
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Nuclear magnetic resonance conformational studies of C-substituted pyrrolecarbaldehydes. Part I. Substituent effects on aldehyde conformations as shown by long range coupling constants
M. Farnier and T. Drakenberg
pg 333; DOI:
10.1039/P29750000333
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Nuclear magnetic resonance conformational studies of C-substituted pyrrolecarbaldehydes. Part II. Barrier to internal rotation in 5-substituted pyrrole-2-carbaldehydes
M. Farnier and T. Drakenberg
pg 337; DOI:
10.1039/P29750000337
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Basic properties of cyclic sulphides and sulphoxides
Ruggero Curci Fulvio Di Furia Arrigo Levi Vittorio Lucchini and Gianfranco Scorrano
pg 341; DOI:
10.1039/P29750000341
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Fourier transform 13C nuclear magnetic resonance studies of steroids. Part I. Some substituted 17-(2,5-dihydro-5-oxo-3-furyl) steroids
Siegmund Lang David N. Lincoln and Victor Wray
pg 344; DOI:
10.1039/P29750000344
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The C–N bond dissociation energy in nitrosyl cyanide
Brian G. Gowenlock Christopher A. F. Johnson Colin M. Keary and Josef Pfab
pg 351; DOI:
10.1039/P29750000351
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Chemistry of sulphines. Part XXVII. Conformational analysis of aryl- and alkyl-thio, aryl- and alkyl-sulphinyl, and aryl- and alkyl-sulphonyl sulphines by means of nuclear magnetic resonance spectra and dipole moments
Albert Tangerman and Binne Zwanenburg
pg 352; DOI:
10.1039/P29750000352
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Dimeric cations from alkanesulphenyl chlorides. The elusive nature of sulphenylium ions
Giuseppe Capozzi Vittorio Lucchini Giorgio Modena and Franco Rivetti
pg 361; DOI:
10.1039/P29750000361
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Semiempirical all-valence-electron calculations on the reactivity of azulene and benzofuran
Estanislao Silla Juan Bertrán and José I. Fernández-Alonso
pg 366; DOI:
10.1039/P29750000366
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Crystal and molecular structure of goniothalamin [(+)-(6S)-5,6-dihydro-6-styryl-2-pyrone]
Peter J. Clarke and Peter J. Pauling
pg 368; DOI:
10.1039/P29750000368
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Transmission of electronic effects by the oxiran ring. Ionization constants of meta- and para-substituted 2,3-epoxy-3-phenylpropionic acids in 50% ethanol
Luigi Standoli
pg 371; DOI:
10.1039/P29750000371
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1,4-Carbonyl participation in solvolysis of alkyl toluene-p-sulphonates
Philip K. G. Hodgson and Stuart Warren
pg 372; DOI:
10.1039/P29750000372
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Organosilicon compounds. Part LIII. Base cleavage of substituted fluoren-9-yltrimethylsilanes and related compounds
Colin Eaborn Kunjitha L. Sinnatambe and David R. M. Walton
pg 380; DOI:
10.1039/P29750000380
PDF
Elimination reactions. Part II. Base-catalysed formation of stilbene derivatives from -phenyl- and -(4-nitrobenzyl)-substituted 4-nitrobenzyl chloride
Rasmy Tewfik Fouad M. Fouad and Patrick G. Farrell
pg 384; DOI:
10.1039/P29750000384
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Reactivity of thiophenoxide ion toward o- and p-halogenonitrobenzenes
Giuseppe Guanti Carlo Dell'Erba Sergio Thea and Giuseppe Leandri
pg 389; DOI:
10.1039/P29750000389
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Conformations of some -unsaturated carbonyl compounds. Part V. Assignments of Raman and infrared spectra of methyl and [2H3]methyl acrylates and trans-crotonates
William O. George David V. Hassid William C. Harris and William F. Maddams
pg 392; DOI:
10.1039/P29750000392
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Conformations of some -unsaturated carbonyl compounds. Part VI. Comparison of out-of-plane olefinic CH deformation vibrations
John R. Cowles William O. George and William G. Fateley
pg 396; DOI:
10.1039/P29750000396
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Conformations of some -unsaturated carbonyl compounds. Part VII. Assignments of Raman and infrared spectra of dimethyl, diethyl, and di-n-butyl fumarates and maleates
David A. C. Compton William O. George and Alan J. Porter
pg 400; DOI:
10.1039/P29750000400
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Crystal and molecular structure of endo,endo-2,6-bis(phenylcarbamoyloxy)-cis-bicyclo[3.3.0]octane
George Ferguson Susan Phillips and Roderic J. Restivo
pg 405; DOI:
10.1039/P29750000405
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Ring-size effects in the oxidation and reduction of some cyclic sulphoxides
Ruggero Curci Fulvio Di Furia Arrigo Levi and Gianfranco Scorrano
pg 408; DOI:
10.1039/P29750000408
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Mechanism of photorearrangement of 6-hydroxybicyclo[3.3.1]nona-3,7-dien-2-ones
Choi-nang Lam and John M. Mellor
pg 412; DOI:
10.1039/P29750000412
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Issue 5


Front cover

pg X017; DOI:
10.1039/P297500FX017
PDF
Contents pages

pg P017; DOI:
10.1039/P297500FP017
PDF
Back cover

pg X019; DOI:
10.1039/P297500BX019
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Excited states of six-membered aza-aromatic rings. Part VIII. Photochemical reactions, fluorescence, and protolytic equilibria in N-alkylated phenazinium ion–phenazyl free radical systems
Wiesawa Rubaszewska and Zbigniew R. Grabowski
pg 417; DOI:
10.1039/P29750000417
PDF
Micellar effects on heteroaromatic compounds. Part I. Nucleophilic substitution of 2-chloroquinoxaline with hydroxide ion
Vito Flamini Paolo Linda and Gianfranco Savelli
pg 421; DOI:
10.1039/P29750000421
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Nitrosyliron complexes with mercapto-purines and -pyrimidines studied by nuclear magnetic and electron spin resonance spectroscopy
R. Basosi E. Gaggelli E. Tiezzi and G. Valensin
pg 423; DOI:
10.1039/P29750000423
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Mechanism of hydrolysis of imidoyl chlorides
Anthony F. Hegarty James D. Cronin and Francis L. Scott
pg 429; DOI:
10.1039/P29750000429
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Reactions of trifluoromethyl radicals. Part I. The photochemical reactions of trifluoroiodomethane with benzene and some halogenobenzenes
J. Michael Birchall Geoffrey P. Irvin and Robert A. Boyson
pg 435; DOI:
10.1039/P29750000435
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Crystal and molecular structure of parthemollin {3,3a,4,5,6,8a-hexahydro-7-(1-hydroxy-3-oxobutyl)-6-methyl-3-methylenecyclohepta[b]-furan-2-one}
P. Sundararaman and Rognvald S. McEwen
pg 440; DOI:
10.1039/P29750000440
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Infrared intensities as a quantitative measure of intramolecular interactions. Part XXXV. Conjugation in para-substituted benzenes and its relation to strain energies and values
T. Bruce Grindley Alan R. Katritzky and Ronald D. Topsom
pg 443; DOI:
10.1039/P29750000443
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Tritium nuclear magnetic resonance spectroscopy. Part III. Coupling constants and isotope effects, and calculation of 2JHH coupling constants
Jasim M. A. Al-Rawi John A. Elvidge John R. Jones and E. Anthony Evans
pg 449; DOI:
10.1039/P29750000449
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35Cl nuclear quadrupole resonance of donor–acceptor complexes. Part II
Soussane Ardjomande and Edwin A. C. Lucken
pg 453; DOI:
10.1039/P29750000453
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Sesquiterpenoids. Part XIX. X-Ray crystallographic determination of the stereochemistry and conformation of the germacranolide glaucolide A
Philip J. Cox and George A. Sim
pg 455; DOI:
10.1039/P29750000455
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Sesquiterpenoids. Part XX. X-Ray crystallographic determination of the molecular structure of berlandin, a guaianolide epoxide. Comments on the circular dichroism of sesquiterpenoid -methylene -lactones with -unsaturated ester side chains
Philip J. Cox George A. Sim and Werner Herz
pg 459; DOI:
10.1039/P29750000459
PDF
Studies in restricted rotation. Part I. Barrier to rotation in some 3-arylcyclohexenone derivatives
Dhanonjoy Nasipuri and Pranab R. Mukherjee
pg 464; DOI:
10.1039/P29750000464
PDF
Stereochemistry of anticholinergic agents. Part VI. Crystal and molecular structure of hexasonium iodide
John J. Guy and Thomas A. Hamor
pg 467; DOI:
10.1039/P29750000467
PDF
The Wallach rearrangement. Part XIV. Rearrangements of azoxynaphthalenes in sulphuric acid. Kinetics and mechanisms
Robin A. Cox Allan J. Dolenko and Erwin Buncel
pg 471; DOI:
10.1039/P29750000471
PDF
Bond scission processes in sulphur compounds. Part IX. Nucleophilic catalysis in the methanolysis of methyl p-nitrophenyl sulphate
Erwin Buncel Claudio Chuaqui Paul Forsythe Susan Mohoney Alain Raoult and James F. Wiltshire
pg 478; DOI:
10.1039/P29750000478
PDF
Interaction of sodium methoxide with 4-nitropyridine N-oxide in benzene in the presence of surfactant aggregates
Eleanor J. Fendler Shuya A. Chang and Janos H. Fendler
pg 482; DOI:
10.1039/P29750000482
PDF
Structure and absolute configuration of plenolin: X-ray analysis of plenolin p-iodobenzoate
Andrew T. McPhail and Kay D. Onan
pg 487; DOI:
10.1039/P29750000487
PDF
Structure and absolute configuration of florilenalin: X-ray analysis of 4-O-acetyl-2-O-p-iodobenzoylflorilenalin
Andrew T. McPhail and Kay D. Onan
pg 492; DOI:
10.1039/P29750000492
PDF
X-Ray determination of the structure and conformation of an oxide from helenalin
Andrew T. McPhail and Kay D. Onan
pg 496; DOI:
10.1039/P29750000496
PDF
Radical anions of trimethylsilyl-substituted NN-dimethylanilines
Il Nam Jung and Paul Ronald Jones
pg 500; DOI:
10.1039/P29750000500
PDF
Participation by neighbouring groups in addition reactions. Part III. Bromination in acetic acid and trifluoroacetic acid solvents
S. Roger Hooley and D. Lyn H. Williams
pg 503; DOI:
10.1039/P29750000503
PDF
Charge-transfer contributions to the stabilisation of the ground state of organic electron donor–acceptor complexes
Roy Foster
pg 507; DOI:
10.1039/P29750000507
PDF

Issue 6


Front cover

pg X021; DOI:
10.1039/P297500FX021
PDF
Contents pages

pg P021; DOI:
10.1039/P297500FP021
PDF
Back cover

pg X023; DOI:
10.1039/P297500BX023
PDF
Mechanism of the reaction of sulphides with N-chloroarenesulphonamides
Ferenc Ruff and Árpád Kucsman
pg 509; DOI:
10.1039/P29750000509
PDF
Influence of a proximate 1,3-diene upon the photoreactivity of some -unsaturated ketones
Choi-nang Lam and John M. Mellor
pg 519; DOI:
10.1039/P29750000519
PDF
Physico-chemical behaviour of sulpha drugs. Spectroscopic trends and conjugation in phenylsulphonylguanidine derivatives
Augusto Rastelli Pier G. De Benedetti Albano Albasini and Pier G. Pecorari
pg 522; DOI:
10.1039/P29750000522
PDF
Electron transfer reaction between 1,3-dinitrobenzene and methyl 1-ethylpyridine-4-carboxylate radical
Mahboob Mohammad
pg 526; DOI:
10.1039/P29750000526
PDF
On the structure of thioamides and their derivatives. Part XXXIII. Kinetics of the acid-catalysed E
Wolfgang Walter Marcia Franzen-Sieveking and Ernst Schaumann
pg 528; DOI:
10.1039/P29750000528
PDF
Oxymetallation. Part VIII. The stereochemistry of peroxymercuration of cyclohexene, norbornene, but-2-ene, and stilbene; intramolecular co-ordination in -peroxyalkylmercury trifluoroacetates
A. J. Bloodworth and I. M. Griffin
pg 531; DOI:
10.1039/P29750000531
PDF
Rotational isomerism. Part XIX. Nuclear magnetic resonance spectral analysis and conformation of 1,1,1,4,4,4-hexafluorobutane
Raymond J. Abraham and Philip Loftus
pg 535; DOI:
10.1039/P29750000535
PDF
13C chemical shifts of 1-substituted camphenes
David G. Morris and A. Malcolm Murray
pg 539; DOI:
10.1039/P29750000539
PDF
Quantitative aspects of Lewis acidity. Part XIII. Basicity of substituted benzamides towards metal halides. The validity of nuclear magnetic resonance chemical shifts as measures of Lewis acid strength
Rosemary S. Satchell Krishna Bukka and Christopher J. Payne
pg 541; DOI:
10.1039/P29750000541
PDF
Acylarylnitrosamines. Part VIII. 15N-Labelling experiments and their relevance to the mechanisms of formation of benzyne from benzenediazonium acetate and of the benzenediazonium ion from hydroxyazo-compounds
J. I. G. Cadogan Charles D. Murray and John T. Sharp
pg 546; DOI:
10.1039/P29750000546
PDF
Aryl and heteroaryl substituent effects in reductions and solvolysis reactions
George T. Bruce A. Roy Cooksey and Keith J. Morgan
pg 551; DOI:
10.1039/P29750000551
PDF
Reduction of nitro- and nitroso-compounds by tervalent phosphorus reagents. Part X. Ring expansion to give 2-diethylamino-3H-azepines
Thymen de Boer J. I. G. Cadogan Miss Helen M. McWilliam and Alan G. Rowley
pg 554; DOI:
10.1039/P29750000554
PDF
Model calculations on thiocarbonyl systems
Gion Calzaferri and Rolf Gleiter
pg 559; DOI:
10.1039/P29750000559
PDF
Proton resonance assignments with the aid of paramagnetic relaxation reagents
G. Victor Fazakerley and Graham E. Jackson
pg 567; DOI:
10.1039/P29750000567
PDF
Intramolecular participation by enolate anions in the cleavage of aryl esters of mesitoic acid; carbon–carbon bond formation in aqueous and alcoholic solvents
H. D. Burrows and R. M. Topping
pg 571; DOI:
10.1039/P29750000571
PDF
Polar addition to olefins. Part II. Stereochemistry of addition of deuterium bromide to cis- and trans-t-butylstyrene. Rotamer populations of sterically crowded trisubstituted ethanes
Raymond J. Abraham and Jose R. Monasterios
pg 574; DOI:
10.1039/P29750000574
PDF
Through-bond charge-transfer interaction in N-(p-methoxyphenylalkyl)pyridinium ions
Anton J. de Gee Jan W. Verhoeven Waltherus J. Sep and Thymen J. de Boer
pg 579; DOI:
10.1039/P29750000579
PDF
Role of molecular packing and structural defects in reactions of gases with organic solids: ozonolysis of trans-stilbene and -diethyl-4,4-dihydroxystilbene
Jean Pierre Desvergne and John M. Thomas
pg 584; DOI:
10.1039/P29750000584
PDF
The trapping of carbon radicals. The competition of oxygen and iodine for the 1,1-diphenylethyl radical
Simon C. W. Hook and Brian Saville
pg 589; DOI:
10.1039/P29750000589
PDF
Some intramolecular reactions of ortho-substituted aryl radicals
Athelstan L. J. Beckwith and William B. Gara
pg 593; DOI:
10.1039/P29750000593
PDF
Crystal structure of the photoaddition product of iodoform and 3,4,5-trimethylphenol
Gary G. Christoph and Everly B. Fleischer
pg 600; DOI:
10.1039/P29750000600
PDF
The infrared bands of thiophen-2-carbaldehydes in the carbonyl region : multiple absorption caused by Fermi resonance
Derek J. Chadwick John Chambers G. Denis Meakins and Roger L. Snowden
pg 604; DOI:
10.1039/P29750000604
PDF
Substituted diphenylmethyl cations. Part I. Acid–base equilibria
Trevor W. Toone Edward Lee-Ruff Prabhaker G. Khazanie and Alan C. Hopkinson
pg 607; DOI:
10.1039/P29750000607
PDF
Studies on the neutral constituents of Pachysandra terminalis Sieb. et Zucc. Part IV. X-Ray structure of 3-O-acetyl-16-O-p-bromobenzoylpachysandiol B: new conformation of a friedelin-type triterpene
Norio Masaki Mineo Niwa and Tohru Kikuchi
pg 610; DOI:
10.1039/P29750000610
PDF
Radiation chemistry of carbohydrates. Part XIX. Yields of trapped electrons and radicals in -irradiated, frozen, concentrated, aqueous solutions of sugars
Jeffrey Bardsley Peter J. Baugh and Glyn O. Phillips
pg 614; DOI:
10.1039/P29750000614
PDF
Linear free energy ortho-correlations in the thiophen series. Part I. The kinetics of piperidinodebromination of some 2-bromo-3-X-5-nitrothiophens in methanol
Domenico Spinelli Giovanni Consiglio Renato Noto and Antonio Corrao
pg 620; DOI:
10.1039/P29750000620
PDF
Substitution at saturated carbon. Part XVIII. The effect of alcoholic solvents on rate constants for SN and SE reactions
Michael H. Abraham and Priscilla L. Grellier
pg 623; DOI:
10.1039/P29750000623
PDF
E1cB and E2cB mechanisms in the elimination of trifluoroethoxide ion from ,-dinitro-,-diphenyl--(trifluoroethoxy)ethanide anion and the non-reactivity of the -cyano-,-dinitro-,-diphenylethanide anion
Michael Albeck Shmaryahu Hoz and Zvi Rappoport
pg 628; DOI:
10.1039/P29750000628
PDF
Reactions of organic sulphur compounds. Part I. The hydrolysis of arenesulphonyl chlorides
Adrian R. Haughton Robert M. Laird and Michael J. Spence
pg 637; DOI:
10.1039/P29750000637
PDF
Reactions of radical anions. Part XV. An electron spin resonance study of the radical anions derived from cis- and trans-1,2-bis(diphenylphosphinyl)ethylene
Alwyn G. Evans Jeffrey C. Evans and Deri Sheppard
pg 643; DOI:
10.1039/P29750000643
PDF
Electrophilic aromatic substitution. Part XIII. Kinetics, isomer yields, and the consequences of ipso-attack in the nitration of toluene and polymethylbenzenes in aqueous sulphuric acid, and their significance for the mechanism of aromatic nitration
James W. Barnett Roy B. Moodie Kenneth Schofield and John B. Weston
pg 648; DOI:
10.1039/P29750000648
PDF
Kinetics and mechanism of the Fischer–Hepp rearrangement and denitrosation. Part VI. The relative reactivity of a number of nitrogen-containing species towards nitrosation, and further evidence against an intermolecular mechanism for the rearrangement
D. Lyn H. Williams
pg 655; DOI:
10.1039/P29750000655
PDF
Nucleophilic and general base catalysis by pyridine and methylpyridines in the hydrolysis of aryl acetates
Anthony R. Butler and Ian H. Robertson
pg 660; DOI:
10.1039/P29750000660
PDF

Issue 7


Front cover

pg X025; DOI:
10.1039/P297500FX025
PDF
Contents pages

pg P025; DOI:
10.1039/P297500FP025
PDF
Back cover

pg X027; DOI:
10.1039/P297500BX027
PDF
Nuclear magnetic resonance spectral study of -aminoenones
Choji Kashima Hiromu Aoyama Yasuhiro Yamamoto Takehiko Nishio and Kazutoshi Yamada
pg 665; DOI:
10.1039/P29750000665
PDF
Optical activity of intermolecular charge-transfer transitions
Anton J. de Gee Waltherus J. Sep Jan W. Verhoeven and Thymen J. de Boer
pg 670; DOI:
10.1039/P29750000670
PDF
Formation of positive ions and other primary species in the oxidation of sulphides by hydroxyl radicals
Marija Bonifai Hermann Möckel Detlef Bahnemann and K.-Dieter Asmus
pg 675; DOI:
10.1039/P29750000675
PDF
The preparation and photolysis of 3-aryl-3H-diazirines
Richard A. G. Smith and Jeremy R. Knowles
pg 686; DOI:
10.1039/P29750000686
PDF
Dipole moments and dielectric relaxation times of some dialkyl and diaryl disulphides and diphenyl disulphone
Manuel J. Aroney Stephen W. Filipczuk and Donald V. Radford
pg 695; DOI:
10.1039/P29750000695
PDF
An electron spin resonance study of reactions of carboxylic acids with the sulphate radical-anion
Wazir C. Vasudeva
pg 697; DOI:
10.1039/P29750000697
PDF
Rotational isomerism. Part XVIII. Rotamer populations in solution of some polychlorinated butanes: a molecular mechanics and nuclear magnetic resonance study
Raymond J. Abraham and Jose R. Monasterios
pg 699; DOI:
10.1039/P29750000699
PDF
Spectrophotometric determination of basicity constants. Part II. Acetanilides
C. Janet Giffney (née Hyland) and Charmian J. O'Connor
pg 706; DOI:
10.1039/P29750000706
PDF
Rearrangement of bifluorenylidene to dibenzo[g,p]chrysene
Roger W. Alder and Graham Whittaker
pg 712; DOI:
10.1039/P29750000712
PDF
The thermal rearrangements of azulenes to naphthalenes
Roger W. Alder and Graham Whittaker
pg 714; DOI:
10.1039/P29750000714
PDF
Electron impact studies. Part XCIV. Retro-Diels–Alder reaction in negative-ion mass spectrometry. Nitro-2H,4H-1,3- and -2,3-dihydro-1,4-benzodioxins
John H. Bowie and Ah Chai Ho
pg 724; DOI:
10.1039/P29750000724
PDF
Benzoquinone imines. Part XII. Reactions of 2-aminoindamines [2-amino-N-(4-aminophenyl)-p-benzoquinone di-imines] in aqueous solution
John F. Corbett Stanley Pohl and Irmina Rodriguez
pg 728; DOI:
10.1039/P29750000728
PDF
Carbon-13 chemical shifts of 4-substituted tricyclenes
David G. Morris and A. Malcolm Murray
pg 734; DOI:
10.1039/P29750000734
PDF
The von Auwers' boiling point rule. A new approach
George M. Kellie and Frank G. Riddell
pg 740; DOI:
10.1039/P29750000740
PDF
Conformations of some 2-substituted furan and thiophen carbonyl compounds
Chun Lai Cheng Ian G. John Geoffrey L. D. Ritchie Peter H. Gore and Leslie Farnell
pg 744; DOI:
10.1039/P29750000744
PDF
Free-radical reductions of arenediazonium ions in aqueous solution. Part III. Kinetics of reactions of toluene-p-diazonium ions with ethanol, propan-2-ol, and acetaldehyde
John E. Packer and Russell K. Richardson
pg 751; DOI:
10.1039/P29750000751
PDF
Relative diffusion coefficients of aromatic cations and aromatic compounds. Justification for directly equating voltammetric potentials to formal potentials
Ulla Svanholm and Vernon D. Parker
pg 755; DOI:
10.1039/P29750000755
PDF
Reactions of oxygenated radicals in the gas phase. Part I. Reaction of peracetyl radicals and but-2-ene
Refugio Ruiz Diaz Keith Selby and David J. Waddington
pg 758; DOI:
10.1039/P29750000758
PDF
Relative reactivities of aliphatic alcohols and amines towards aminyl radicals
Giuseppe Farnia Renato Tomat and Elio Vianello
pg 763; DOI:
10.1039/P29750000763
PDF
Electron paramagnetic resonance parameters and equilibria of manganese(II)–amino-acid complexes in aqueous solution
E. Tiezzi
pg 769; DOI:
10.1039/P29750000769
PDF
Crystal structure of oxotremorine sesquioxalate, 1-[4-(2-oxopyrrolidin-1-yl)but-2-ynyl]pyrrolidinium sesquioxalate
Peter J. Clarke Peter J. Pauling and Trevor J. Petcher
pg 774; DOI:
10.1039/P29750000774
PDF
The kinetics and mechanism of the reaction between mercury(II) ions and thiobenzamides in aqueous solution
Alan J. Hall and Derek P. N. Satchell
pg 778; DOI:
10.1039/P29750000778
PDF
Determination of pK values of peptide groups in dipeptides from nuclear magnetic resonance kinetic studies
M. Sheinblatt and Y. Rahamin
pg 784; DOI:
10.1039/P29750000784
PDF
Electrophilic aromatic substitution. Part XIV. Kinetics of nitration of some aromatic sulphonic acids in sulphuric acid
Roy B. Moodie Kenneth Schofield and Tadao Yoshida
pg 788; DOI:
10.1039/P29750000788
PDF
Interaction between phenol and electron donors in cyclohexane and carbon tetrachloride
Keith M. C. Davis James A. Deuchar and Douglas A. Ibbitson
pg 793; DOI:
10.1039/P29750000793
PDF
Mechanism of cyclization of aryl radicals containing unsaturated ortho-substituents
Athelstan L. J. Beckwith and William B. Gara
pg 795; DOI:
10.1039/P29750000795
PDF
Dehalogenation reactions of vicinal dihalides. Part IV. Kinetics of amine-promoted eliminations of 1-chloro-2-iodo-1,2-diphenylethane in aqueous dioxan
Enrico Baciocchi and Claudio Lillocci
pg 802; DOI:
10.1039/P29750000802
PDF

Issue 8


Front cover

pg X029; DOI:
10.1039/P297500FX029
PDF
Contents pages

pg P029; DOI:
10.1039/P297500FP029
PDF
Back cover

pg X031; DOI:
10.1039/P297500BX031
PDF
The darzens condensation. Part III. Effects of substituents on the rate of condensation of substituted phenacyl chlorides with benzaldehyde
György Sipos Gy. Schöbel and F. Sirokmán
pg 805; DOI:
10.1039/P29750000805
PDF
-Sulphonylenamines. An X-ray and 1H nuclear magnetic resonance study of the stereochemistry of the isomeric -chloromethylsulphonyl--methyl--morpholinostyrenes
(Mrs) Paola Del Buttero Stefano Maiorana Giovanni Dario Andreetti Gabriele Bocelli and Paolo Sgarabotto
pg 809; DOI:
10.1039/P29750000809
PDF
Nucleophilic substitutions in five-membered rings. Primary steric effects in thiophen derivatives
Domenico Spinelli Giovanni Consiglio and Tommaso Monti
pg 816; DOI:
10.1039/P29750000816
PDF
Kinetics of protolytic and keto–enol reactions of some 5-monosubstituted barbituric acids
Hans Koffer
pg 819; DOI:
10.1039/P29750000819
PDF
Kinetic study of E2 eliminations from 2-thienylethyl bromides and toluene-p-sulphonates promoted by sodium ethoxide in ethanol
Enrico Baciocchi Vittorio Mancini and Piero Perucci
pg 821; DOI:
10.1039/P29750000821
PDF
The stabilities of Meisenheimer complexes. Part X. Association of 1,1-dimethoxy-complexes with cations
Michael R. Crampton
pg 825; DOI:
10.1039/P29750000825
PDF
Kinetics of the liquid-phase hydrogenation of aromatic nitro-compounds in the presence of tungsten carbide catalyst
György Horányi and György Vértes
pg 827; DOI:
10.1039/P29750000827
PDF
Polysaccharide conformation. Part VIII. Test of energy functions by Monte Carlo calculations for monosaccharides
David A. Rees and Peter J. C. Smith
pg 830; DOI:
10.1039/P29750000830
PDF
Polysaccharide conformation. Part IX. Monte Carlo calculation of conformational energies for disaccharides and comparison with experiment
David A. Rees and Peter J. C. Smith
pg 836; DOI:
10.1039/P29750000836
PDF
The electronic structure of conjugated molecules. Non-empirical calculations for the benzenium, pyridinium, pyrylium, and thiopyrylium cations and a comparison of the last with phosphorin
Michael H. Palmer Robert H. Findlay William Moyes and Anthony J. Gaskell
pg 841; DOI:
10.1039/P29750000841
PDF
Triple oxidations of some polyhydric phenols by cerium(IV) in acid solutions as observed by electron spin resonance spectroscopy
William T. Dixon and David Murphy
pg 850; DOI:
10.1039/P29750000850
PDF
The Jaff reaction. Part II. A kinetic study of the Janovsky complexes formed from creatinine(2-imino-1-methylimazolidin-4-one) and acetone
Anthony R. Butler
pg 853; DOI:
10.1039/P29750000853
PDF
Nucleophilic substitution at sulphinyl sulphur. Kinetics and oxygen-18 tracer studies of the alkaline hydrolysis of some sulphinate esters
Aziz A. Najam and John G. Tillett
pg 858; DOI:
10.1039/P29750000858
PDF
Carbon-13 nuclear magnetic resonance spectra of some epoxides
Stephen G. Davies and Gordon H. Whitham
pg 861; DOI:
10.1039/P29750000861
PDF
Nucleophilic attacks on carbon–carbon double bonds. Part XXII. Base catalysis, leaving group effects, and solvent effects in several nucleophilic vinylic substitutions by amines
Zvi Rappoport and Alain Topol
pg 863; DOI:
10.1039/P29750000863
PDF
Aromatic reactivity. Part LIX. Substituent effects of groups of type CH2Y in acid cleavage of p-YCH2C6H4SiMe3 compounds and on the charge-transfer maxima of YCH2Ph–tetracyanoethylene complexes
Andrew J. Cornish and Colin Eaborn
pg 874; DOI:
10.1039/P29750000874
PDF
The acidities of weak acids. Part II. Some acetophenones
Derek W. Earls John R. Jones and Trevor G. Rumney
pg 878; DOI:
10.1039/P29750000878
PDF

Issue 9


Front cover

pg X033; DOI:
10.1039/P297500FX033
PDF
Contents pages

pg P033; DOI:
10.1039/P297500FP033
PDF
Back cover

pg X035; DOI:
10.1039/P297500BX035
PDF
Partitioning of reverse activation energy between kinetic and internal energy in reactions of some simple organic ions
Georg Hvistendahl and Dudley H. Williams
pg 881; DOI:
10.1039/P29750000881
PDF
Electron spin resonance studies. Part XLV. Reactions of the methyl radical with some aliphatic compounds in aqueous solution
Bruce C. Gilbert Richard O. C. Norman Giuseppe Placucci and Roger C. Sealy
pg 885; DOI:
10.1039/P29750000885
PDF
Electron spin resonance studies. Part XLVI. Oxidation of thiols and disulphides in aqueous solution: formation of RS, RSO, RSO2, RSSR, and carbon radicals
Bruce C. Gilbert Hugh A. H. Laue Richard O. C. Norman and Roger C. Sealy
pg 892; DOI:
10.1039/P29750000892
PDF
Reactions of sulphenyl chlorides and disulphides in acidic media. Trapping of alkyl(bisalkylthio)sulphonium ion intermediates
Giuseppe Capozzi Vittorio Lucchini Giorgio Modena and Franco Rivetti
pg 900; DOI:
10.1039/P29750000900
PDF
Electric dipole moments of some tetra- and penta-fluorobenzenes
Hsing Hua Huang
pg 903; DOI:
10.1039/P29750000903
PDF
Grisorixin, an ionophorous antibiotic of the nigericin group. Part IV. Complexation of monovalent cations
Pierre Gachon Gérard Chaput Georges Jeminet Jean Juillard and Jean-Pierre Morel
pg 907; DOI:
10.1039/P29750000907
PDF
Kinetics and mechanism of the reaction of methyl iodide with silver perchlorate in nitromethane
Dennis N. Kevill Vinay V. Likhite and Hans S. Posselt
pg 911; DOI:
10.1039/P29750000911
PDF
Chemistry of sulphines. Part XXVIII. Barriers to rotation in highly substituted arylthio, alkyl- and aryl-sulphinyl, and arylsulphonyl E- and Z-sulphines
Albert Tangerman and Binne Zwanenburg
pg 916; DOI:
10.1039/P29750000916
PDF
Nuclear magnetic resonance investigations of carbonium ion intermediates. Part III. A chlorine-35 quadrupole resonance study of several (R-chloromethylene)dimethylammonium salts (Vilsmeier–Haack and Viehe reagents)
Gérard Jugie John A. S. Smith and Gérard J. Martin
pg 925; DOI:
10.1039/P29750000925
PDF
19F and 1H nuclear magnetic resonance studies of ring-fluorinated imidazoles and histidines
Herman J. C. Yeh Kenneth L. Kirk Louis A. Cohen and Jack S. Cohen
pg 928; DOI:
10.1039/P29750000928
PDF
The kinetics of photochemical reactions. Part IV. Photoreduction of carbonyl triplets by bonds other than C–H. Semiempirical calculations
Carlos M. Previtali and Juan C. Scaiano
pg 934; DOI:
10.1039/P29750000934
PDF
Carbon-13 nuclear magnetic resonance spectra of some polyphosphines with ethane bridges between trivalent phosphorus atoms
R. Bruce King and John C. Cloyd jun.
pg 938; DOI:
10.1039/P29750000938
PDF
Salt effects on the rates of protonation of amides
Brian G. Cox and Paolo De Maria
pg 942; DOI:
10.1039/P29750000942
PDF
Nitration of triptycene in acetic anhydride
John H. Rees
pg 945; DOI:
10.1039/P29750000945
PDF
The oxazolinone intermediate in the hydrolysis and aminolysis of N-benzoylglycine derivatives
Andrew Williams
pg 947; DOI:
10.1039/P29750000947
PDF
Kinetics and mechanism of the reaction between copper(II) ions and thiobenzamide in aqueous solution
Alan J. Hall and Derek P. N. Satchell
pg 953; DOI:
10.1039/P29750000953
PDF
Molecular complexes. Part XIV. Proton magnetic resonance studies of the interactions of chloroform with benzene and some alkylbenzenes at various temperatures
John Homer and Paul M. Whitney
pg 956; DOI:
10.1039/P29750000956
PDF
Halogeno-1,4-dioxans and their derivatives. Part VII. Conformations and 1H nuclear magnetic resonance parameters of some chloro-1,4-dioxans and 5-chloro-2,3-dihydro-1,4-dioxin
Robert E. Ardrey and Leslie A. Cort
pg 959; DOI:
10.1039/P29750000959
PDF
Nucleophilic substitution at trigonal carbon. Part II. Ethanolysis of aliphatic acyl chlorides
Dennis N. Kevill Peter H. Daum and Rekha Sapre
pg 963; DOI:
10.1039/P29750000963
PDF
Aromatic sulphonation. Part XLIX. Sulphonation of anthracene and some meso-substituted hydrocarbon derivatives: mechanism of methyl side-chain sulphonation
Hans Cerfontain Ankie Koeberg-Telder Cornelis Ris and Cees Schenk
pg 966; DOI:
10.1039/P29750000966
PDF
Aromatic sulphonation. Part L. Sulphonation of the trimethylbenzenes: isomer distributions and hydrogen kinetic isotope effect
Hans Cerfontain Ankie Koeberg-Telder Cornelis Ris and Zwaan R. H. Schaasberg-Nienhuis
pg 970; DOI:
10.1039/P29750000970
PDF
Non-empirical calculations of the electronic structure of some five-membered ring heterocycles containing sulphur and phosphorus: thiophen and phosphole
Michael H. Palmer and Robert H. Findlay
pg 974; DOI:
10.1039/P29750000974
PDF
Nucleophilic attacks on carbon–carbon double bonds. Part XXIII. Substitution of -chloro--phenylacrylonitriles
Zvi Rappoport and Alain Topol
pg 982; DOI:
10.1039/P29750000982
PDF

Issue 10


Front cover

pg X037; DOI:
10.1039/P297500FX037
PDF
Contents pages

pg P037; DOI:
10.1039/P297500FP037
PDF
Back cover

pg X039; DOI:
10.1039/P297500BX039
PDF
Linear free energy relationships in the thiophen series. Part I. Leaving group effect in piperidino-substitution in methanol of some 2-L-3-nitro-5-X-thiophens
Domenico Spinelli and Giovanni Consiglio
pg 989; DOI:
10.1039/P29750000989
PDF
Crystal structure of 2,3-epithio-5-androst-6-en-17-yl p-bromobenzoate
Kazuko Utsumi-Oda and Hirozo Koyama
pg 993; DOI:
10.1039/P29750000993
PDF
Conformational studies of 2,3-diacyl-5-nitrocyclopentadienes: delocalized systems with very short intramolecular O H O hydrogen bonds. Crystal and molecular structures of 2,3-diacetyl- and 2,3-dibenzoyl-5-nitrocyclopentadiene
George Ferguson Wayne C. Marsh Roderic J. Restivo and Douglas Lloyd
pg 998; DOI:
10.1039/P29750000998
PDF
Stereoselectivity and stereospecificity in electron deficient diene cycloadditions with norbornadiene and 7-t-butoxynorbornadiene: results and MINDO/2 theoretical study
K. Brian Astin and Kenneth Mackenzie
pg 1004; DOI:
10.1039/P29750001004
PDF
Aminolysis and base-catalysed hydrolysis of aryl phenylphosphonamidates and amidothionates: reactions close to the E1cB–bimolecular nucleophilic mechanistic borderline
Andrew Williams Kenneth T. Douglas and John S. Loran
pg 1010; DOI:
10.1039/P29750001010
PDF
On the theory of structure–reactivity relationships
Martin Godfrey
pg 1016; DOI:
10.1039/P29750001016
PDF
Crystal and molecular structure of silver sulphadiazine (N1-pyrimidin-2-ylsulphanilamide)
David S. Cook and Michael F. Turner
pg 1021; DOI:
10.1039/P29750001021
PDF
The nature of the transition state in ester pyrolysis. Part II. The relative rates of pyrolysis of ethyl, isopropyl, and t-butyl acetates, phenylacetates, benzoates, phenyl carbonates, and N-phenylcarbamates
Roger Taylor
pg 1025; DOI:
10.1039/P29750001025
PDF
Structural investigations of ylides. Part VI. Crystal and molecular structures of two resonance-stabilized Wittig reagents 2-carboxy-1-methoxycarbonylethyltriphenylphosphorane and its t-butyl ester
A. Forbes Cameron Fergus D. Duncanson Andrew A. Freer Victor W. Armstrong and Robert Ramage
pg 1030; DOI:
10.1039/P29750001030
PDF
Iodine atom-catalysed isomerisation of substituted cis,trans-1,4-diphenylbutadienes
Anton J. G. van Rossum Anton H. M. de Bruin and Rutger J. F. Nivard
pg 1036; DOI:
10.1039/P29750001036
PDF
Iodine atom-catalysed isomerisation of cis,trans,trans- and trans,cis,-trans-1,6-diphenylhexa-1,3,5-trienes and of trans,cis,trans,trans-1,8-dphenylocta-1,3,5,7-tetraene
Anton J. G. van Rossum and Rutger J. F. Nivard
pg 1042; DOI:
10.1039/P29750001042
PDF
Sequential displacement of chloride in N-aryl-and N-aroyl-carbonimidoyl dichlorides
Anthony F. Hegarty and Kieran J. Dignam
pg 1046; DOI:
10.1039/P29750001046
PDF
Carbene chemistry. Part VIII. The thermal decomposition of trichloromethyltrifluorosilane: a kinetic investigation
Frederick Anderson J. Michael Birchall Robert N. Haszeldine and Brian J. Tyler
pg 1051; DOI:
10.1039/P29750001051
PDF
Intramolecular alkylation of phenols. Part I. Mechanism of phenoxide cyclisation
Patrick G. Duggan and William S. Murphy
pg 1054; DOI:
10.1039/P29750001054
PDF
The acid–base function in non-aqueous solution. Part V. Entropy changes due to intramolecular and solvation effects in aprotic solvents
Dayaram M. Parbhoo Deenadayalan K. Chetty and John W. Bayles
pg 1057; DOI:
10.1039/P29750001057
PDF
Crystal and molecular structure of trans-4-aminocrotonic acid
Graham P. Jones and Peter J. Pauling
pg 1059; DOI:
10.1039/P29750001059
PDF
Kinetic comparison of the relative susceptibility to steric hindrance of an intra- and an inter-molecular cleavage of the ester bond in a series of 2- and 4-carbamoylphenyl esters of 2,4,6-trialkylated benzoic acids
Peter L. Russell and Richard M. Topping
pg 1062; DOI:
10.1039/P29750001062
PDF
3-Methyl-5-phenylpyrazole: a neutron diffraction study
Frank H. Moore Allan H. White and Anthony C. Willis
pg 1068; DOI:
10.1039/P29750001068
PDF
Crystal structure of the 1 : 1 molecular complex of chrysene and tetrafluoro-p-benzoquinone (fluoranil)
Peter J. Munnoch and John D. Wright
pg 1071; DOI:
10.1039/P29750001071
PDF
Stereochemistry of anticholinergic agents. Part VII. Crystal and molecular structure of 3-(2-methylpiperidino)-1-phenylpropyl phenyl ether methiodide
John J. Guy and Thomas A. Hamor
pg 1074; DOI:
10.1039/P29750001074
PDF
Heterocyclic free radicals. Part V. An electron spin resonance investigation of the cation-radicals of 10-phenylphenoxazine and 10-phenylphenothiazine
David Clarke Bruce C. Gilbert and Peter Hanson
pg 1078; DOI:
10.1039/P29750001078
PDF
Investigations of structure and conformation. Part V. Conformational interconversion and ring shape in five- and six-membered alicyclic radicals
Bruce C. Gilbert and Michael Trenwith
pg 1083; DOI:
10.1039/P29750001083
PDF
Mechanistic studies in strongly basic media. Part VIII. Kinetic studies on the displacement of halide from benzyl halides by alkali-metal salts of 9-substituted fluorenes in t-butyl alcohol solution
Donald Bethell Colin S. Fairclough and Rodney G. Wilkinson
pg 1090; DOI:
10.1039/P29750001090
PDF
Vibrational M–O bands of acetylacetone–metal complexes
Shraga Pinchas and Jacob Shamir
pg 1098; DOI:
10.1039/P29750001098
PDF
A nuclear magnetic resonance study of the conformational equilibrium in fluorosulphonylethanes
Giuseppe Marchese Francesco Naso Domenico Santo and Oronzo Sciacovelli
pg 1100; DOI:
10.1039/P29750001100
PDF
Crystal structure of the reversed carboxy-analogue of acetylcholine [methyl 3-(dimethylamino)propionate methiodide]
Peter J. Clarke and Peter J. Pauling
pg 1107; DOI:
10.1039/P29750001107
PDF
Quantitative aspects of Lewis acidity. Part XIV. Comparison of the acidity of tin tetrachloride, tellurium tetrachloride, and zirconium tetrabromide towards substituted anilines in dioxan
Krishna Bukka and Rosemary S. Satchell
pg 1110; DOI:
10.1039/P29750001110
PDF
General acid catalysed hydrolysis of benzaldehyde aryl methyl acetals
Brian Capon and Keith Nimmo
pg 1113; DOI:
10.1039/P29750001113
PDF
Mechanisms of ring opening of oxirans by acids in aqueous and non-aqueous solvents
Gérard Lamaty Robert Maleq Claude Selve André Sivade and James Wylde
pg 1119; DOI:
10.1039/P29750001119
PDF
Crystal structures and absolute stereochemistry of tecomanine methoperchlorate and alkaloid C methiodide: two monoterpene alkaloids from Tecoma stans
George Ferguson and Wayne C. Marsh
pg 1124; DOI:
10.1039/P29750001124
PDF

Issue 11


Front cover

pg X041; DOI:
10.1039/P297500FX041
PDF
Contents pages

pg P041; DOI:
10.1039/P297500FP041
PDF
Back cover

pg X043; DOI:
10.1039/P297500BX043
PDF
X-Ray crystal structure of 1,3,6,8-tetraoxacyclodecane
Ivaro W. Bassi Raimondo Scordamaglia and Leonardo Fiore
pg 1129; DOI:
10.1039/P29750001129
PDF
Reactions of amines and active methylene compounds with buta-1,3-diene and isoprene: catalysis by nickel, cobalt, rhodium, and iridium complexes
Raymond Baker Alan Onions Roger J. Popplestone and Trevor N. Smith
pg 1133; DOI:
10.1039/P29750001133
PDF
The reactivity of O-acylglycosyl halides. Part XII. Solvent effects on exchange and hydrolysis reactions
Michael J. Duffy Geoffrey Pass Glyn O. Phillips and Abdul Samee
pg 1138; DOI:
10.1039/P29750001138
PDF
Crystal and molecular structure of the 1 : 2 complex of methyltriphenylphosphonium with -tetracyano-3,7-naphthoquinodimethane, (Ph3PMe)+[(tnap)2]
F. Sanz and J. J. Daly
pg 1141; DOI:
10.1039/P29750001141
PDF
Crystal and molecular structure of the 2 : 3 complex of N-methylphenazinium with -tetracyanoquinodimethane, [(nmp)2]2+[(tcnq)3]2–
F. Sanz and J. J. Daly
pg 1146; DOI:
10.1039/P29750001146
PDF
The kinetics and mechanisms of additions to olefinic substances. Part XII. Kinetics of addition initiated by chlorine acetate
Peter B. D. de la Mare Charmian J. O'Connor and Michael A. Wilson
pg 1150; DOI:
10.1039/P29750001150
PDF
Raman spectral investigation of the interactions between group II cations and ethylene glycol in aqueous solutions
Robert M. Williams and Rajai H. Atalla
pg 1155; DOI:
10.1039/P29750001155
PDF
Reaction of aromatic amides with phenyl iodosylacetate: an oxidative rearrangement
K. Swaminathan and N. Venkatasubramanian
pg 1161; DOI:
10.1039/P29750001161
PDF
The reactivity of phenyl isocyanate in aqueous solution
Anthony F. Hegarty Con N. Hegarty and Francis L. Scott
pg 1166; DOI:
10.1039/P29750001166
PDF
An X-ray study of the p-n-alkoxybenzoic acids. Part III. Crystal structure of p-ethoxybenzoic acid
Robert F. Bryan and Jacqueline J. Jenkins
pg 1171; DOI:
10.1039/P29750001171
PDF
An X-ray study of the p-n-alkoxybenzoic acids. Part IV. Crystal structure of p-n-butoxybenzoic acid
Robert F. Bryan and Lawrence Fallon III
pg 1175; DOI:
10.1039/P29750001175
PDF
Crystal structure and conformation of 17-ethynyl-17-hydroxy-6,6-di-methyl-6-sila-5-estr-1(10)-en-3-one
Andrew T. McPhail and Richard W. Miller
pg 1180; DOI:
10.1039/P29750001180
PDF
Reduction of nitro- and nitroso-compounds by tervalent phosphorus reagents. Part XI. A kinetic study of the effects of varying the reagent and the nitro-compound in the conversion of o-nitrobenzylideneamines to 2-substituted indazoles
Margaret-Ann Armour J. I. G. Cadogan and David S. B. Grace
pg 1185; DOI:
10.1039/P29750001185
PDF
Electron spin resonance study of the stereochemistry of radicals related to cinnamic acid
William T. Dixon Majid Moghimi and David Murphy
pg 1189; DOI:
10.1039/P29750001189
PDF
The conformational analysis of saturated heterocycles. Part LXX. Nitrogen inversions in 1,3,4-oxadiazolidines
Victor J. Baker Alan R. Katritzky and Jean-Pierre Majoral
pg 1191; DOI:
10.1039/P29750001191
PDF
Gas-phase eliminations. Part XIV. The pyrolysis of 1-(1-chloroethyl)-2-methylbenzene
Allan Maccoll and (Mrs) Mirtha Umaña
pg 1194; DOI:
10.1039/P29750001194
PDF
Substitution effects in kinetically controlled reactions
Peter Luby
pg 1196; DOI:
10.1039/P29750001196
PDF
Tetrazole studies. Part III. Crystal structure of 5-[(3-chlorobenzyl)dimethylammonio] tetrazolide
Gerald B. Ansell
pg 1200; DOI:
10.1039/P29750001200
PDF
Acid catalysed hydrolysis of N-alkyl-4-chlorobenzamides. Part II.
C. Janet Giffney (née Hyland) and Charmian J. O'Connor
pg 1203; DOI:
10.1039/P29750001203
PDF
Spectrophotometric determination of basicity constants. Part III. Phenylureas
C. Janet Giffney (née Hyland) and Charmian J. O'Connor
pg 1206; DOI:
10.1039/P29750001206
PDF
The mechanism of diazo-coupling to indoles and the effect of steric hindrance on the rate-limiting step
Brian C. Challis and Henry S. Rzepa
pg 1209; DOI:
10.1039/P29750001209
PDF
Solvent dependence of the primary deuterium kinetic isotope effect in the sodium hydroxide-catalysed E2 elimination of hydrogen bromide from p-acetyl- and p-nitro-phenethyl bromide
Leonard F. Blackwell and John L. Woodhead
pg 1218; DOI:
10.1039/P29750001218
PDF
Reactivities of polystyrene and polypropylene toward t-butoxyl radical. Effects of molecular weight, solvent, and temperature
Etsuo Niki and Yoshio Kamiya
pg 1221; DOI:
10.1039/P29750001221
PDF
Non-empirical calculations of the nature of the bonding in thiophen, thiophen S-oxide, and thiophen SS-dioxide
Michael H. Palmer and Robert H. Findlay
pg 1223; DOI:
10.1039/P29750001223
PDF
The acidites of weak acids. Part III. Some 3-benzoyl-1,1,1-trifluoroacetones
John R. Jones and Suryakant P. Patel
pg 1231; DOI:
10.1039/P29750001231
PDF
Magnetic double resonance studies of tin-119 chemical shifts in compounds with tin–sulphur bonds and related species
John D. Kennedy William McFarlane Geoffrey S. Pyne Peter L. Clarke and James L. Wardell
pg 1234; DOI:
10.1039/P29750001234
PDF
Chiroptical properties of lactones. Part I. Rotatory strengths of electronic transitions in substituted and unsubstituted 1,4-dioxan-2,5-diones (dilactones)
Frederick S. Richardson and Neal Cox
pg 1240; DOI:
10.1039/P29750001240
PDF
Electron spin resonance studies. Part XLVII. Sulphinyl- and sulphonyl-substituted aliphatic radicals
Paul M. Carton Bruce C. Gilbert Hugh A. H. Laue Richard O. C. Norman and Roger C. Sealy
pg 1245; DOI:
10.1039/P29750001245
PDF
Chlorine-35 nuclear quadrupole resonance spectra of chlorodiazines
Christopher J. Turner
pg 1250; DOI:
10.1039/P29750001250
PDF

Issue 12


Front cover

pg X045; DOI:
10.1039/P297500FX045
PDF
Contents pages

pg P045; DOI:
10.1039/P297500FP045
PDF
Back cover

pg X047; DOI:
10.1039/P297500BX047
PDF
Photochemical cleavage of the cyclopropane ring of 6,20-epoxylathyrol {1,11-diacetoxy-3,6,6,14-tetramethyl-13-phenylacetoxy(tricyclo[10.3.0.0]pentadec-3-ene-10-spiro-2-oxiran)-2-one}
Allan Balmain
pg 1253; DOI:
10.1039/P29750001253
PDF
1:1, 2:1, and Apparent association constants for a series of electron donor–acceptor complexes involving 1,3,5-trinitrobenzene and tetrafluoro-p-benzoquinone (fluoranil)
Alan A. S. Bright John A. Chudek and Roy Foster
pg 1256; DOI:
10.1039/P29750001256
PDF
The photochemistry of benz[de]anthracen-7-ones. Part II. Flash photolysis
Peter Bentley John F. McKellar and Glyn O. Phillips
pg 1259; DOI:
10.1039/P29750001259
PDF
Electron spin resonance studies of aromatic hydrocarbon radical ions. Part IV. t-Butylacenaphthene anions
Alan S. Huffadine Barrie M. Peake and Leslie W. Deady
pg 1263; DOI:
10.1039/P29750001263
PDF
Kinetics of reactions in heterocycles. Part XIII. Substituted N-methylpyridinium and N-methylquinolinium salts with piperidine in water and in ethanol
Gordon B. Barlin and John A. Benbow
pg 1267; DOI:
10.1039/P29750001267
PDF
Refinement of the crystal structure of orthorhombic dibenz[a,h]-anthracene
John Iball Colin H. Morgan and David E. Zacharias
pg 1271; DOI:
10.1039/P29750001271
PDF
Reactions of silver ions with thiobenzamides in aqueous solution
Alan J. Hall and Derek P. N. Satchell
pg 1273; DOI:
10.1039/P29750001273
PDF
Chiroptical properties of lactones. Part II. Electronic rotatory strengths of the n* transition in saturated - and -lactones
Frederick S. Richardson and William Pitts
pg 1276; DOI:
10.1039/P29750001276
PDF
Crystal and molecular structure of 2-(m-bromophenyl)-3-methyl-4-(trifluoroacetyl)oxazolium 5-oxide, a mesoionic oxazolone
Gerhard V. Boyd Colin G. Davies John D. Donaldson Jack Silver and Peter H. Wright
pg 1280; DOI:
10.1039/P29750001280
PDF
Photochemistry of non-conjugated dienones. Part V. Photolysis of (E)--ionone and its isomeric -pyran
Albert van Wageningen Hans Cerfontain and Jan A. J. Geenevasen
pg 1283; DOI:
10.1039/P29750001283
PDF
Electrophilic aromatic substitution. Part XVI. Detritiation and desilylation of 1,6-methano[10]annulene and 11,11-difluoro-1,6-methano[10]annulene
Roger Taylor
pg 1287; DOI:
10.1039/P29750001287
PDF
Intramolecular alkylation of phenols. Part II. ortho-versus para- Alkylation
Patrick G. Duggan and William S. Murphy
pg 1291; DOI:
10.1039/P29750001291
PDF
Interaction between the carbonyl group and a sulphur atom. Part VI. Some 3-thiacycloalkanones
Bernadette T. Buzzi Paulo R. Olivato Roberto Rittner Constantino Trufen Hans Viertler and Blanka Wladislaw
pg 1294; DOI:
10.1039/P29750001294
PDF
Rapid deuteriation and tritiation of organic compounds using organometallic and elemental halides as catalysts
Mervyn A. Long John L. Garnett and Ross F. W. Vining
pg 1298; DOI:
10.1039/P29750001298
PDF
Radical-anion intermediates. Part VII. Reactions of the 1,2,3,4-tetraphenylcyclopenta-1,3-diene radical anion
Brian J. Tabner and Timothy Walker
pg 1304; DOI:
10.1039/P29750001304
PDF
Applications of high potential quinones. Part IX. A stereoelectronic effect in the rates of quinone dehydrogenation of benzocycloalkenols
David R. Brown and Alan B. Turner
pg 1307; DOI:
10.1039/P29750001307
PDF
Bipyridyl radical cations. Part I. Electron spin resonance study of the dimerisation equilibrium of morphamquat radical cation in methanol
Alwyn G. Evans Jeffrey C. Evans and Michael W. Baker
pg 1310; DOI:
10.1039/P29750001310
PDF
Coupling of diazonium salts with acetone
Nabil K. Masoud Alfy Badie Sakla Zaki Sawiris and Nadia A. Yassa
pg 1312; DOI:
10.1039/P29750001312
PDF
Kinetics and mechanism of N–H and C–H isotopic exchange in pyrrole and indole: acid-catalysed exchange in aqueous acetonitrile solutions
David M. Muir and Mark C. Whiting
pg 1316; DOI:
10.1039/P29750001316
PDF
Cyanoporphyrins. Co-ordinating and electrochemical properties
Henry J. Callot Alain Giraudeau and Maurice Gross
pg 1321; DOI:
10.1039/P29750001321
PDF
Substituent and solvent effects on the Diels–Alder reactions of triazolinediones
Martin E. Burrage Richard C. Cookson Surash S. Gupte and Ian D. R. Stevens
pg 1325; DOI:
10.1039/P29750001325
PDF
Radiation chemistry of carbohydrates. Part V. -Radiolysis of scyllo-inositol in deoxygenated and oxygenated aqueous solution
Andrée Kirsch Clemens von Sonntag and Dietrich Schulte-Frohlinde
pg 1334; DOI:
10.1039/P29750001334
PDF
Radiation chemistry of alcohols. Part XXI. Ultraviolet photolysis ( 185 nm) of methoxyethanol in the liquid phase
Raymond Ford Heinz-Peter Schuchmann and Clemens von Sonntag
pg 1338; DOI:
10.1039/P29750001338
PDF
Intra- and inter-molecular catalysis in the halogenation of some oxocarboxylic acids
Ronald P. Bell and Anthony D. Covington
pg 1343; DOI:
10.1039/P29750001343
PDF
A relaxation study of the isomerisation of 2,2,3-trimethyl-levulinic acid
Ronald P. Bell and Brian G. Cox
pg 1349; DOI:
10.1039/P29750001349
PDF
Reactions between tetrachlorogold(III) ions and N-cyclohexylthiobenzamide
Alan J. Hall and Derek P. N. Satchell
pg 1351; DOI:
10.1039/P29750001351
PDF
A dynamic nuclear magnetic resonance study of ring inversion occurring in 1,4-oxa-thian, -selenan, and -telluran
John C. Barnes Geoffrey Hunter and Malcolm W. Lown
pg 1354; DOI:
10.1039/P29750001354
PDF
Acid catalysed hydrolysis of substituted acetanilides. Part II
C. Janet Giffney and Charmian J. O'Connor
pg 1357; DOI:
10.1039/P29750001357
PDF

Issue 13


Front cover

pg X049; DOI:
10.1039/P297500FX049
PDF
Contents pages

pg P049; DOI:
10.1039/P297500FP049
PDF
Back cover

pg X051; DOI:
10.1039/P297500BX051
PDF
Crystal and molecular structure of 17-hydroxy-17-methyl-2-oxa-5-androstan-3-one
David F. Rendle and James Trotter
pg 1361; DOI:
10.1039/P29750001361
PDF
Calculations of steric effects. Part II. The SN2 halide exchange reactions
Michael H. Abraham Priscilla L. Grellier and Malcolm J. Hogarth
pg 1365; DOI:
10.1039/P29750001365
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Infrared intensities as a quantitative measure of intramolecular interactions. Part XLII. 1,2-Disubstituted ethylenes
George Peter Ford Alan Roy Katritzky and Ronald D. Topsom
pg 1371; DOI:
10.1039/P29750001371
PDF
Infrared intensities as a quantitative measure of intramolecular interactions. Part XLIII. Quantitative estimation of electronic interactions in mono- and di-substituted ethylenes and the prediction of rotational barriers
George P. Ford Alan R. Katritzky and Ronald D. Topsom
pg 1378; DOI:
10.1039/P29750001378
PDF
Investigation of photolysis of o-nitrophenols by electron spin resonance spectroscopy. Characterisation of 1,2-benzoquinone monohydroxyimine free radicals
Robert G. Green Leslie H. Sutcliffe and Peter N. Preston
pg 1380; DOI:
10.1039/P29750001380
PDF
Kinetics of reactions in heterocycles. Part XIV. Reactions of 2- and 4-amino-, -methylamino-, and -dimethylamino-pyridine methiodides and 2-methylthiopyrimidine methiodide with hydroxide ions in water
Gordon B. Barlin and John A. Benbow
pg 1385; DOI:
10.1039/P29750001385
PDF
Nucleophilic substitution in five-membered rings. Influence of steric interactions in the reaction area on activation by a nitro-group
Domenico Spinelli and Giovanni Consiglio
pg 1388; DOI:
10.1039/P29750001388
PDF
Generation of glycopyranosyl cations in the spontaneous hydrolyses of 2,4-dinitrophenyl glycopyranosides. Evidence for the general intermediacy of glycopyranosyl cations in the acid-catalysed hydrolyses of methyl glycopyranosides
David Cocker and Michael L. Sinnott
pg 1391; DOI:
10.1039/P29750001391
PDF
Relationship between the magnitude of Jgem and the spatial orientation of -substituents
Roger Davies and John Hudec
pg 1395; DOI:
10.1039/P29750001395
PDF
Relationship between the magnitude of Jgem and the spatial orientation of -substituents
Roger Davies
pg 1400; DOI:
10.1039/P29750001400
PDF
Enthalpies of ionization deduced from the temperature dependence of indicator measurements for amides in concentrated aqueous solutions of perchloric acid
Salem A. Attiga and Colin H. Rochester
pg 1411; DOI:
10.1039/P29750001411
PDF
Direct carbon-13 nuclear magnetic resonance study of boron trifluoride and boron trichloride complexes with ethers
Anthony Fratiello Robert Kubo David Liu and George Vidulich
pg 1415; DOI:
10.1039/P29750001415
PDF
Conformation and circular dichroism of uronic acid residues in glycosides and polysaccharides
Edwin R. Morris David A. Rees George R. Sanderson and David Thom
pg 1418; DOI:
10.1039/P29750001418
PDF
Retentive solvolysis. Part X. Retentive solvolysis of optically active para-substituted 1-phenylethyl p-nitrobenzoates in phenolic solvents: rate, steric course, product distribution, and mechanism
Kunio Okamoto Tomomi Kinoshita Yoichi Takemura and Haruyuki Yoneda
pg 1426; DOI:
10.1039/P29750001426
PDF
Nuclear magnetic resonance experiments on acetals. Part LVIII. Conformational studies of 4-methylene-1,3-dioxan
Marc J. Anteunis and Rudi Camerlynck
pg 1434; DOI:
10.1039/P29750001434
PDF
Aromatic sulphonation. Part LI. Sulphonation of 1,3,5-tri- and m- and p-di-t-butylbenzene, the three t-butylbenzenesulphonic acids, and 3,5-di-t-butylbenzenesulphonic acid
Cornelis Ris and Hans Cerfontain
pg 1438; DOI:
10.1039/P29750001438
PDF
Classical carbonium ions. Part IV. Absence of hydride shift in the solvolysis of 1- and 2-adamantyl toluene-p-sulphonate
Michael L. Sinnott and Mark C. Whiting
pg 1446; DOI:
10.1039/P29750001446
PDF
Classical carbonium ions. Part V. Stereochemistry of substitution in the solvolysis of 2-adamantyl and 2-methyl-2-adamantyl derivatives
John A. Bone John R. Pritt and Mark C. Whiting
pg 1447; DOI:
10.1039/P29750001447
PDF
Classical carbonium ions. Part VI. Rearrangement during acetolysis of some 2-adamantyl derivatives
Hans J. Storesund and Mark C. Whiting
pg 1452; DOI:
10.1039/P29750001452
PDF
Classical carbonium ions. Part VII. Nucleophilic assistance by solvent during acetolysis of secondary alkyl derivatives
John R. Pritt and Mark C. Whiting
pg 1458; DOI:
10.1039/P29750001458
PDF
Electrophilic aromatic reactivities via pyrolysis of 1-arylethyl acetates. Part XI. The + value for the m-methyl substituent
Ernest Glyde and Roger Taylor
pg 1463; DOI:
10.1039/P29750001463
PDF
Thermal rearrangement of some 1- and 2-substituted azulenes to naphthalenes
Roger W. Alder and Colin Wilshire
pg 1464; DOI:
10.1039/P29750001464
PDF

Issue 14


Front cover

pg X053; DOI:
10.1039/P297500FX053
PDF
Contents pages

pg P053; DOI:
10.1039/P297500FP053
PDF
Back cover

pg X055; DOI:
10.1039/P297500BX055
PDF
Nucleophilic reactivity of methoxide ion at C-5 of 4-nitro-7-X-benzofurazans: a kinetic and thermodynamic investigation of Meisenheimer complexes
Leonardo Di Nunno Saverio Florio and Paolo E. Todesco
pg 1469; DOI:
10.1039/P29750001469
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Ring opening and closing in heterocyclic compounds. 1H nuclear magnetic resonance studies on the reaction between 6-nitrobenzothiazole and methoxide ion in dimethyl sulphoxide–methanol
Giuseppe Bartoli Francesco Ciminale and Paolo E. Todesco
pg 1472; DOI:
10.1039/P29750001472
PDF
Reactions of aryl isothiocyanates with dicyclohexylcarbodi-imide. Search for the mechanism of cycloaddition and cycloreversion
Alessandro Dondoni and Arturo Battaglia
pg 1475; DOI:
10.1039/P29750001475
PDF
Properties of polyamide-based catalysts. Part I. Hydrodehalogenation of chlorobenzene
Paolo Dini Jan C. J. Bart and Nicola Giordano
pg 1479; DOI:
10.1039/P29750001479
PDF
X-Ray determination of the structure of podolide, an antileukemic norditerpene dilactone
Robert F. Bryan and Peter M. Smith
pg 1482; DOI:
10.1039/P29750001482
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Transition state enthalpies of transfer from propanol to acetonitrile in the reaction of imidazole with benzoyl and benzenesulphonyl chlorides
Otto Rogne
pg 1486; DOI:
10.1039/P29750001486
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Substituent effect in the reaction of aryl arylmercury sulphides with picryl iodide
G. Guanti M. Novi C. Dell'Erba and G. Leandri
pg 1490; DOI:
10.1039/P29750001490
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Unstable intermediates. Part CLIX. Dihalide anions and related species as products in the radiolysis of organic halides
Shuddhodan P. Mishra and Martyn C. R. Symons
pg 1492; DOI:
10.1039/P29750001492
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The chemistry of nitroso-compounds. Part X. Acid catalysed nitrosation of azulene and 1-nitroazulene
Brian C. Challis and Richard J. Higgins
pg 1498; DOI:
10.1039/P29750001498
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Aromatic chlorination by peroxodisulphate and chloride ions. Cation radical trapping by copper(II) chloride
Anthony Ledwith and Peter J. Russell
pg 1503; DOI:
10.1039/P29750001503
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Structure of pentafluorobenzaldehyde determined from nuclear magnetic resonance spectra of nematic solutions
James W. Emsley John C. Lindon and David S. Stephenson
pg 1508; DOI:
10.1039/P29750001508
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Kinetics of the intramolecular displacement of alcohols from o-hydroxyaminobenzoates
Brian G. Cox Duncan McL. A. Grieve and Alexander E. A. Porter
pg 1512; DOI:
10.1039/P29750001512
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Molecular orbital and strain energy investigations of the photocyclization of 1,2-di--naphthylethylene
Karol A. Muszkat S. Sharafi-Ozeri Georg Seger and T. A. Pakkanen
pg 1515; DOI:
10.1039/P29750001515
PDF
Induced circular dichroism. Part III. Chiroptical properties and ionpair equilibria in 2-benzoylbenzoic acid–amphetamine
Shunsuke Takenaka Keizo Kondo and Niichiro Tokura
pg 1520; DOI:
10.1039/P29750001520
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Kinetics of intramolecular acylation of 3-(2-hydroxybenzylidene)-4,5-dihydrofuran-2(3H)-one in concentrated acids
Ignazio R. Bellobono Bruno Marcandalli Luciano Zanderighi and Cornelia Parini
pg 1525; DOI:
10.1039/P29750001525
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Photochemical intramolecular acylation of 3-(2-hydroxybenzylidene)-4,5-dihydrofuran-2(3H)-one in methanol
Ignazio R. Bellobono Luciano Zanderighi Silvano Omarini Bruno Marcandalli and Cornelia Parini
pg 1529; DOI:
10.1039/P29750001529
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The polarography of some oxonium ions in methylene chloride. Part I. Experimental techniques and results for two tertiary ions
Peter H. Plesch and Francis G. Thomas
pg 1532; DOI:
10.1039/P29750001532
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Dynamic stereochemistry of imines and derivatives. Part V. Acid catalysis of EZ imine interconversion
W. Brian Jennings Salim Al-Showiman Malcolm S. Tolley and Derek R. Boyd
pg 1535; DOI:
10.1039/P29750001535
PDF
Thermodynamic functions of proton ionisation of meta-substituted benzenethiols
Paolo De Maria Adamo Fini and Francis M. Hall
pg 1540; DOI:
10.1039/P29750001540
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Structure and conformation of 4,4-bipyridyl by nuclear magnetic resonance spectroscopy of a nematic solution
James W. Emsley David S. Stephenson John C. Lindon Ludovico Lunazzi and Svano Pulga
pg 1541; DOI:
10.1039/P29750001541
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Proton nuclear magnetic resonance spectra and conformation in 1,4-dihydrobenzenes and 9,10-dihydroanthracenes
Martin C. Grossel and M. John Perkins
pg 1544; DOI:
10.1039/P29750001544
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Crystal structure of the acid salts of some dibasic acids. Part IX. Potassium hydrogen meso-tartrate: a neutron diffraction study
Murdoch Currie J. Clare Speakman Jan A. Kanters and Jan Kroon
pg 1549; DOI:
10.1039/P29750001549
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Reaction studies at high pressure. Part I. Activation volumes of some[2 + 2] and dipolar cycloadditions
Neil S. Isaacs and Erwin Rannala
pg 1555; DOI:
10.1039/P29750001555
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Infrared and nuclear magnetic resonance absorption and isomerism of 3-aminocrotonic esters. Part III
Antonio Gómez Sánchez and Juana Bellanato
pg 1561; DOI:
10.1039/P29750001561
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Absolute configuration of (+)-trans-chrysanthemic acid. Crystal structure analysis of a p-bromoanilide derivative
A. Forbes Cameron George Ferguson and Christine Hannaway
pg 1567; DOI:
10.1039/P29750001567
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Emissions of sterically hindered stilbene derivatives and related compounds. Part IV. Large conformational differences between ground and excited states of sterically hindered stilbenes: implications regarding stokes shifts and viscosity or temperature dependence of fluorescence yields
Gabriela Fischer Georg Seger Karol A. Muszkat and Ernst Fischer
pg 1569; DOI:
10.1039/P29750001569
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The photoluminescence of some -nitrostyrenes. Excited state energies in unsaturated nitro-compounds
David J. Cowley
pg 1576; DOI:
10.1039/P29750001576
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Theoretical study of the 4-pyridylmethyl and the 2- and 5-pyrimidyl-methyl cations and radicals
Charles U. Pittman jun. Maurice R. Smith Gary D. Nichols Shing K. Wuu and Lowell D. Kispert
pg 1581; DOI:
10.1039/P29750001581
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The chemistry of reactive lignin intermediates. Part II. Addition reactions of vinyl-substituted quinone methides in aqueous solution
Jacqueline A. Hemmingson and Gordon Leary
pg 1584; DOI:
10.1039/P29750001584
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Dipole moments of methyl- and trifluoromethyl-substituted methyl benzoates
Geoffrey Hallas John D. Hepworth Douglas A. Ibbitson and Donald E. Thornton
pg 1587; DOI:
10.1039/P29750001587
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Kinetics of oxidation of secondary alcohols by chloramine T
M. M. Natarajan and V. Thiagarajan
pg 1590; DOI:
10.1039/P29750001590
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Kinetics of hydrogen isotope exchange reactions. Part XXX. Steric course of -radiation-induced exchange between water and tartaric acids
Marcello Colosimo James P. Garvey Victor Gold and Eric Leonidou
pg 1595; DOI:
10.1039/P29750001595
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Crystal and molecular structure of 8a-bromo-1,2,3,5,6,7,8,8a-octahydro-1,3-dioxoisoquinoline-4-carbonitrile
Tayur N. Guru Row Kailasam Venkatesan Vijay K. Sharma and Tirumalai R. Kasturi
pg 1597; DOI:
10.1039/P29750001597
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The standardization of aromatic and heteroaromatic nitration rates
Alan R. Katritzky Bulent Terem Eric V. Scriven Sergio Clementi and H. Okan Tarhan
pg 1600; DOI:
10.1039/P29750001600
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The kinetics and mechanism of the electrophilic substitution of hetero-aromatic compounds. Part XLI. Nitration of 3-hydroxy-1-phenyl-pyrazoles
Mehmet Dereli Alan R. Katritzky and H. Okan Tarhan
pg 1609; DOI:
10.1039/P29750001609
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The kinetics and mechanism of the electrophilic substitution of heteroaromatic compounds. Part XLII. The nitration of thiazoles and thiazolones
Alan R. Katritzky Cemil Ögretir H. Okan Tarhan Henri M. Dou and Jacques V. Metzger
pg 1614; DOI:
10.1039/P29750001614
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The kinetics and mechanism of the electrophilic substitution of heteroaromatic compounds. Part XLIII. The nitration of isothiazoles
Alan R. Katritzky H. Okan Tarhan and Bulent Terem
pg 1620; DOI:
10.1039/P29750001620
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Discussion of standard nitration rates for benzenoid and heteroaromatic compounds
Alan R. Katritzky Sergio Clementi and H. Okan Tarhan
pg 1624; DOI:
10.1039/P29750001624
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The kinetics and mechanism of the electrophilic substitution of heteroaromatic compounds. Part XLVII. Nitration of phenylisoxazoles
Alan R. Katritzky Mustafa Konya H. Okan Tarhan and Alan G. Burton
pg 1627; DOI:
10.1039/P29750001627
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The kinetics and mechanism of the electrophilic substitution of heteroaromatic compounds. Part XLVIII. Nitration of pyrazoles in the 3- and 5-positions
Alan R. Katritzky H. Okan Tarhan and Bulent Terem
pg 1632; DOI:
10.1039/P29750001632
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Pseudoaromatic compounds. Part XXII. Reactions of 2-functionalized tropones with sodium toluene-p-thiolate
Marino Cavazza Gino Biggi Francesco Del Cima and Francesco Pietra
pg 1636; DOI:
10.1039/P29750001636
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Radiation effects on aryl glycosides. Part VII. Radiolysis of aqueous solutions of p-nitrophenyl -D-glucopyranoside
Kenneth Kemsley John S. Moore and Glyn O. Phillips
pg 1638; DOI:
10.1039/P29750001638
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Ultrasonic relaxation associated with nitrogen and ring inversion in some piperidines, piperidones, morpholines, and piperazines
Vivian M. Gittins Peter J. Heywood and Evan Wyn-Jones
pg 1642; DOI:
10.1039/P29750001642
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Solvolytic behaviour of cis- and trans-[5-2H1]cyclo-octyl p-bromo-benzenesulphonate—a stereospecific, remote ?-deuterium isotope effect
William Parker and C. Ian F. Watt
pg 1647; DOI:
10.1039/P29750001647
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Electron spin resonance spectrum of the xanthen radical anion
Pierre Lambelet and Edwin A. C. Lucken
pg 1652; DOI:
10.1039/P29750001652
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Observation of stable arylalkoxycarbenium ions: a nuclear magnetic resonance study
Daniel Bruck and Mordecai Rabinovitz
pg 1656; DOI:
10.1039/P29750001656
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Ion-pairing of substituted 1,3-diphenylallyl carbanions with alkalimetal cations
Geoffrey C. Greenacre and Ronald N. Young
pg 1661; DOI:
10.1039/P29750001661
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Phenyl participation in the generation of carbocations from the reactions of some 1-methyl--phenylalkyl toluene-p-sulphonates and -phenylalk-1-enes in trifluoroacetic acid
Timothy J. Mason
pg 1664; DOI:
10.1039/P29750001664
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Stereochemistry of elimination reactions of 2-chloro-1-phenylpropane in different solvent–base systems
Sergio Alunni Enrico Baciocchi Rosario Nicoletti and Marco Tingoli
pg 1669; DOI:
10.1039/P29750001669
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Issue 15


Front cover

pg X057; DOI:
10.1039/P297500FX057
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Contents pages

pg P057; DOI:
10.1039/P297500FP057
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Back cover

pg X059; DOI:
10.1039/P297500BX059
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Nematic phase nuclear magnetic resonance, ultrasonic relaxation, and theoretical ab initio investigation of internal rotation in pyridine-2-carbaldehyde
Giovanni Conti Enrico Matteoli Carlo Petrongolo Carlo A. Veracini and Marcello Longeri
pg 1673; DOI:
10.1039/P29750001673
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Application of reaction field theory to the calculation of solvent effects on the Menschutkin reaction of tripropylamine with methyl iodide
Michael H. Abraham and Raymond J. Abraham
pg 1677; DOI:
10.1039/P29750001677
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Nuclear magnetic resonance studies on benzaldehydes. Part II. Carbon-13 nuclear magnetic resonance studies of the barrier to internal rotation and the conformational equilibrium in o- and m-substituted benzaldehydes
T. Drakenberg R. Jost and J. M. Sommer
pg 1682; DOI:
10.1039/P29750001682
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Crystal structures of (5E,12E)-7-acetoxy-15-hydroxybertya-5,12-diene-3,14-dione and (5E,12E)-7-acetoxybertya-5,12-diene-3,14-dione
Edward N. Maslen Robert F. Toia Allan H. White and Anthony C. Willis
pg 1684; DOI:
10.1039/P29750001684
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Hindered internal rotation in 3,4-di-isopropyl-4-thiazoline-2-thione from temperature-dependent nuclear magnetic resonance spectra of five different groups of protons: a methodological study
Robert E. Carter Torbjörn Drakenberg and Christian Roussel
pg 1690; DOI:
10.1039/P29750001690
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Reactivity of indazoles and benzotriazole towards N-methylation and analysis of the 1H nuclear magnetic resonance spectra of indazoles and benzotriazoles
Michael H. Palmer Robert H. Findlay Sheila M. F. Kennedy and Peter S. McIntyre
pg 1695; DOI:
10.1039/P29750001695
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Thermal dealkylation of 2,4-bisalkylamino-6-chloro-s-triazines. Effect of alkyl group structure on dealkylation
Milan D. Mukatirovi and ivorad D. Tadi
pg 1701; DOI:
10.1039/P29750001701
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Assignment and conformational properties of the exocyclic 5-hydroxy-methyl group of nucleosides by nuclear magnetic resonance spectroscopy
David B. Davies and Andrzej Rabczenko
pg 1703; DOI:
10.1039/P29750001703
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Synthesis, electronic spectra, and photoisomerization of naphthyl-pyridylethylenes
Guido Galiazzo Pietro Bortolus and Fausto Masetti
pg 1712; DOI:
10.1039/P29750001712
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Reactions of oxygenated radicals in the gas phase. Part II. Reactions of peracetyl radicals and butenes
Keith Selby and David J. Waddington
pg 1715; DOI:
10.1039/P29750001715
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Effect of chain length on the chemical ionisation mass spectra of methyl n-alkanoates
Chun Wai Tsang and Alex G. Harrison
pg 1718; DOI:
10.1039/P29750001718
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Molecular orbital calculations on the C2H4SH+ cation
James W. Gordon George H. Schmid and Imre G. Csizmadia
pg 1722; DOI:
10.1039/P29750001722
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Cyclization of 3-allylhex-5-enyl radical: mechanism, and implications concerning the structures of cyclopolymers
Athelstan L. J. Beckwith and Graeme Moad
pg 1726; DOI:
10.1039/P29750001726
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Kinetics and equilibria of the S-nitrosation of alkylthioureas
Peter Collings Khawla Al-Mallah and Geoffrey Stedman
pg 1734; DOI:
10.1039/P29750001734
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Investigation of phosphorus–carbon bond lengths in aromatic phosphines. Part I. Crystal and molecular structures of tri-o-tolylphosphine, -phosphine oxide, -phosphine sulphide, and -phosphine selenide
T. Stanley Cameron and Birgitta Dahlèn
pg 1737; DOI:
10.1039/P29750001737
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Intermediates in nucleophilic aromatic substitution. Part XIV. Interaction of lyate ions with polynitronaphthalenes
Willie L. Hinze Li-Jen Liu and Janos H. Fendler
pg 1751; DOI:
10.1039/P29750001751
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Intermediates in nucleophilic aromatic substitution. Part XV. Thermodynamic stabilities of hydroxy and methoxy Meisenheimer complexes of substituted arenes
Janos H. Fendler Willie L. Hinze and Li-Jen Liu
pg 1768; DOI:
10.1039/P29750001768
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INDO theoretical studies of 4-aminopyridine and protonated 4-aminopyridine
Charles U. Pittman jun. Onallah M. Attallah and Lowell D. Kispert
pg 1776; DOI:
10.1039/P29750001776
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Reaction of 2-hydroxy-5-nitrotoluene--sulphonic acid sultone with nucleophiles
Timothy Deacon Alex Steltner and Andrew Williams
pg 1778; DOI:
10.1039/P29750001778
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Electrophilic aromatic reactivities via pyrolysis of 1-arylethyl acetates. Part XII. Total reactivity of isoquinoline
Ernest Glyde and Roger Taylor
pg 1783; DOI:
10.1039/P29750001783
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Kinetics of the decomposition of some 1-pyrazolines
Donald E. McGreer Ian M. E. Masters and Michael T. H. Liu
pg 1791; DOI:
10.1039/P29750001791
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Structure of 2,3,5,6-tetrafluoroanisole determined from the analysis of a nuclear magnetic resonance spectrum of a nematic solution
James W. Emsley John C. Lindon and David S. Stephenson
pg 1794; DOI:
10.1039/P29750001794
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Crystal and molecular structure of eupatolide, the major cytotoxic principle from Eupatorium formosanum HAY
Andrew T. McPhail and Kay D. Onan
pg 1798; DOI:
10.1039/P29750001798
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The nature of the transition state in ester pyrolysis. Part III. The Hammett correlation for pyrolysis of t-butyl benzoates
Hassan B. Amin and Roger Taylor
pg 1802; DOI:
10.1039/P29750001802
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1,2-Cycloaddition of -unsaturated esters to a biased enamine. Crystal and molecular structure of a cis-bicyclo[4.2.0]octane derivative
Sergio Brückner Giuliana Pitacco and Ennio Valentin
pg 1804; DOI:
10.1039/P29750001804
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Studies on the reactions between nitric oxide and conjugated dienes
Peter B. Brindley and Simon H. Nicholson
pg 1808; DOI:
10.1039/P29750001808
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Dynamic stereochemistry of imines and derivatives. Part VI. Stereochemistry of the peroxyacid–imine route to oxaziridines
Derek R. Boyd David C. Neill Christopher G. Watson and W. Brian Jennings
pg 1813; DOI:
10.1039/P29750001813
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Crystal and molecular structure of the enol form of 1,1-diphenyl-2,2-dithiobis(butane-1,3-dione)
Leslie F. Power Raymond D. G. Jones James Pletcher and Martin Sax
pg 1818; DOI:
10.1039/P29750001818
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Heteroaromatic hydrogen exchange reactions. Part VIII. The ionisation of 1,3-dimethylindolin-2-one
Brian C. Challis and Henry S. Rzepa
pg 1822; DOI:
10.1039/P29750001822
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Sesquiterpenoids. Part XXI. Conformations of the episantonins: crystal structures of 2-bromo-6-epi--santonin and 2-bromo-6-epi--santonin
David N. J. White and George A. Sim
pg 1826; DOI:
10.1039/P29750001826
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A study of bipyridyl radical cations. Part II. The reaction of morphamquat {bis-N-[(2,6-dimethylmorpholin-4-yl)carbonylmethyl]-4,4-bipyridylium} radical cation with oxygen in methanol
Alwyn G. Evans Raymond E. Alford and Norman H. Rees
pg 1831; DOI:
10.1039/P29750001831
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Crystal structures of -trans- and p-methoxy-cinnamic acids and their relation to thermal mesomorphism
Robert F. Bryan and Derek P. Freyberg
pg 1835; DOI:
10.1039/P29750001835
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Free radical addition to olefins. Part XVI. Photolysis of difluoroiodomethane in the presence of olefins
John P. Sloan John M. Tedder and John C. Walton
pg 1841; DOI:
10.1039/P29750001841
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Free radical addition to olefins. Part XVII. Addition of fluoroiodomethane to fluoroethylenes
John P. Sloan John M. Tedder and John C. Walton
pg 1846; DOI:
10.1039/P29750001846
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Secondary kinetic isotope effects and the intervention of non-classical ions in the solvolysis of endo-bicyclo[3.2.1]octan-2-yl toluene-p-sulphonate
H. Maskill
pg 1850; DOI:
10.1039/P29750001850
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Substitution at saturated carbon. Part XIX. The effect of alcohols and water on the free energy of solutes and on the free energy of transition states in SN and SE reactions
Michael H. Abraham and Priscilla L. Grellier
pg 1856; DOI:
10.1039/P29750001856
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Stereochemistry of freelingyne [(4Z,6E)-9-(3-furyl)-2,6-dimethylnona-2,4,6-trien-8-yn-4-olide] by X-ray analysis
Michael J. Begley David W. Knight and Gerald Pattenden
pg 1863; DOI:
10.1039/P29750001863
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Physical and chemical quenching of excited uranyl ion by organic molecules studied by fluorimetric and laser flash photolysis methods
Mahmood Ahmad Alan Cox Terence J. Kemp and Qaisar Sultana
pg 1867; DOI:
10.1039/P29750001867
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Kinetics and mechanism of iodination of 8-hydroxyquinoline
Alan A. Humffray and Darryl R. Schroeter
pg 1873; DOI:
10.1039/P29750001873
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